To convert the mass of an electron from kg to MeV/c^2, use Einstein's equation E=mc^2. The mass of the electron is approximately 9.11 x 10^-31 kg, and when plugged into the equation, it yields an energy of about 8.2 x 10^-14 joules. Converting joules to electronvolts using the conversion factor of 1 eV = 1.602 x 10^-19 joules results in approximately 0.512 MeV. Thus, the mass of the electron can be expressed as 0.512 MeV/c^2. This process illustrates the conversion between mass and energy units effectively.