Classical and Quantum Statistics

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Homework Help Overview

The discussion revolves around a problem in statistical mechanics, specifically focusing on the behavior of an atom with a magnetic moment in a uniform magnetic field at a given temperature. The original poster is tasked with finding the ratio of atoms with spins aligned with the magnetic field to those aligned opposite, while considering the applicability of Maxwell-Boltzmann statistics.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to determine the appropriate statistical distribution to use, expressing confusion between Maxwell-Boltzmann and Fermi-Dirac statistics. They also raise questions about the density of states and the role of the magnetic field. Other participants suggest treating the spins as two species of particles and discuss the implications of chemical potential and energy states related to spin orientation.

Discussion Status

The discussion is ongoing, with participants exploring different interpretations of the problem. Some guidance has been offered regarding the use of classical Boltzmann statistics and the treatment of spins, but there is still uncertainty about the density of states and the relationship between energy and spin orientation.

Contextual Notes

Participants are grappling with the definitions and implications of terms like chemical potential and density of states in the context of the problem. There is also a recognition of the need to clarify how the magnetic field influences the energy states of the spins.

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Homework Statement


Consider an atom with a magnetic moment \mu and a total spin of ½. The atom is placed in a uniform magnetic field B at temperature T. (a) Assuming Maxwell-Boltzmann statistics are valid at this temperature, find the ratio of atoms with spins aligned with the field to those aligned opposite the field.

Homework Equations


n\left(E\right)=g\left(E\right)F and the corresponding equation for F depending on Maxwell-Boltzmann, Fermi-Dirac, or Bose-Einstein

The Attempt at a Solution


I'm having a little trouble figuring out which distribution function to use. I want to say that it's Fermi-Dirac because of the half-integer spin, but the question states that Maxwell-Boltzmann statistics are valid, which throws me off. And I'm still a little confused about the density of states. And where the magnetic field factors into my equation.
 
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As the question states, you can use classical Boltzmann statistics. What you need is an expression for the chemical potential. Treat up spins and down spins as two species of "particle". In an external B field, these species have different energies, and so there will be a chemical potential for one of them to change into the other. Once you figure that out, you just need the Boltzmann factor.
 
So are you saying we have 2 possible states, making the density of states two (either up spin or down spin)?

I'm not sure what you mean by chemical potential, but I'm assuming you're talking about the potential due to intrinsic spin, so V=-\vec{\mu_{s}}\bullet\vec{B}, which would make the potential either \pm\mu_{B}B. And that would make the energy in the distribution function E_{0}+V. Is that right?
 
Ok so my equation for the ratio is \frac{n\left(E_{2}\right)}{n\left(E_{1}\right)}=\frac{g\left(E_{2}\right)}{g\left(E_{1}\right)}e^{\beta\left(E_{1}-E_{2}\right)} with E_{1}-E_{2}=2\mu_{B}B. I still don't know how to find the density of states. I want to say for each one it is two because the energies depend on the direction of the spin, so for each energy state it is either an +1/2 or -1/2 spin.
 
That's good so far. In this particular problem, does g(E) actually depend on energy?
 
Well the energy for each state depends on the direction of the spin, +1/2 or -1/2, so I feel like there is only one orientation for each state. At the very least, the density of states for each one should be equal. I think?
 

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