Compton vs Photoelectric effect?

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Discussion Overview

The discussion focuses on the differences and similarities between the Compton effect (CE) and the photoelectric effect (PE), exploring their mechanisms, conditions for occurrence, and contexts in which they apply. Participants examine theoretical aspects, experimental observations, and definitions related to these phenomena.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Exploratory

Main Points Raised

  • Some participants propose that CE and PE are fundamentally different processes, with CE involving elastic scattering of photons and PE involving complete absorption of photon energy by an electron.
  • Others argue that the occurrence of PE depends on the photon matching a transition state in the atom, while CE occurs when the photon does not match these states.
  • A few participants suggest that the energy of the photon plays a significant role, with PE dominating at lower energies and CE becoming more probable at higher energies.
  • One participant notes that the standard photoelectric effect does not occur in gases, where the term photoionization is more appropriate due to the absence of continuous energy bands.
  • Some contributions highlight that the reaction rate for both effects increases with electron density, which varies with the state of the material (solid, liquid, gas).
  • There is mention of experimental observations where the number of Compton interactions can exceed that of photoelectric interactions at higher gamma energies.
  • A participant raises a question about the confusion surrounding the definitions of PE and CE, particularly in the context of nuclear engineering and health physics.

Areas of Agreement / Disagreement

Participants express multiple competing views regarding the definitions and conditions for CE and PE, indicating that the discussion remains unresolved with no consensus reached.

Contextual Notes

Some statements reflect limitations in definitions, such as the distinction between photoelectric effect and photoionization, and the role of energy bands in solids versus gases. The discussion also highlights the dependence of outcomes on photon energy and material properties.

pivoxa15
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What is the main differences? Are they essentially the same thing?

From what I have gathered, the two are fundalmentally the same. If a photon gives up all its energy after interaction with an electron than the photoelectric effect applies.
On the other hand if the photon continues to travel and possesses kinetic energy after collision with an electron than the Compton effect takes place.

Also it seems the photoelectric effect happens mainly with electrons in metals whereas the Compton effect is with any material.
 
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pivoxa15 said:
What is the main differences? Are they essentially the same thing?

From what I have gathered, the two are fundalmentally the same. If a photon gives up all its energy after interaction with an electron than the photoelectric effect applies.
On the other hand if the photon continues to travel and possesses kinetic energy after collision with an electron than the Compton effect takes place.

Also it seems the photoelectric effect happens mainly with electrons in metals whereas the Compton effect is with any material.

They are completely different.

In CE, a photon is elastically scattered by a charge which recoils.
Conservation of energy and momentum results in a change in the energy and momentum of the photon (usually measured as a change in wave length).

In PE, a photon is completely absorbed by a solid, and an electron is ejected in the process.
 
What determines whether CE or PE occurs? Why is it that sometimes, an electron is able to absorb all of the photon's energy (PE) and sometimes, it just gets pushed around like a "ball collision" (CE)?

I'll have a guess. Is it because PE occurs only if the photon matches a transition state in the atom? Hence the electron is able to completely absorb the photon's energy. When it doesn't occur (i.e. energies don't match) than you get CE?
 
pivoxa15 said:
What determines whether CE or PE occurs? Why is it that sometimes, an electron is able to absorb all of the photon's energy (PE) and sometimes, it just gets pushed around like a "ball collision" (CE)?

I'll have a guess. Is it because PE occurs only if the photon matches a transition state in the atom? Hence the electron is able to completely absorb the photon's energy. When it doesn't occur (i.e. energies don't match) than you get CE?

There are no more "atoms" in a solid. The energy bands that you get in a solid such as a metal is the collective effect of all the atoms in such a way that you no longer get the individual atomic behavior. That is why you get band of energy, rather than discrete states of atoms.

Photoelectric effect will only occur in solids due to the requirement of longitudinal momentum conservatoin. Compton effect occurs when a photon encounter a "free" particle or atoms. It can occur, in a limited sense, in solids, but the effect isn't dominant when compared with other phenomena that can occur.

Zz.
 
pivoxa15 said:
What determines whether CE or PE occurs? Why is it that sometimes, an electron is able to absorb all of the photon's energy (PE) and sometimes, it just gets pushed around like a "ball collision" (CE)?

I'll have a guess. Is it because PE occurs only if the photon matches a transition state in the atom? Hence the electron is able to completely absorb the photon's energy. When it doesn't occur (i.e. energies don't match) than you get CE?
If one looks at the cross-sections of PE and CE, one finds that PE dominates at lower energies. As gamma energy increases, the probability of Compton scattering increases.

PE and CE occur in solid, liquid or gaseous states of any element. The reaction rate increases with electron density, which is a function of the element and state (solid, liquid or gas).
 
Astronuc said:
PE and CE occur in solid, liquid or gaseous states of any element. The reaction rate increases with electron density, which is a function of the element and state (solid, liquid or gas).

The standard Photoelectric effect doesn't actually occur in gasses. That is more commonly called photoionization. This is different than photoelectric effect because you don't have a continuous energy bands, and you also don't have a "work function".

Zz.
 
ZapperZ said:
The standard Photoelectric effect doesn't actually occur in gasses. That is more commonly called photoionization. This is different than photoelectric effect because you don't have a continuous energy bands, and you also don't have a "work function".
It maybe that nuclear engineers are abusing the term 'photoelectric'. I learned PE means the electron absorbs the photon completely, which is also photoionziation. I think we (nuclear engineers and radiation physicists) misappopriated the term. :smile:

I was wondering about the distinction between the classic 'photoelectric' effect where if the photon (on order of a few eV's) strikes a metal surface resulting in the ejection of a photo-electron, and the interaction of a keV X-ray or gamma-ray which strikes any atomic electron and is completely absorbed. For nuclear engineers and health physicists, there is not distinction. If a photon is completely absorbed, then we called it 'photoelectric effect' and the ejected electron is a photo-electron.
 
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ZapperZ said:
Compton effect occurs when a photon encounter a "free" particle or atoms. It can occur, in a limited sense, in solids, but the effect isn't dominant when compared with other phenomena that can occur.

That depends of course on the energy of the photon. In one of our undergraduate labs, students send 662-keV gammas from Cs-137 into a NaI scintilator and do a pulse-height analysis of the spectrum that comes out of the scintillator's photodetector. I don't have a spectrum handy here at home, but the numbers of pulses from photoelectric and Compton interactions are in the same general ballpark, with probably more Comptons.

For higher-energy gammas, say the approx. 1.2 MeV ones from Co-60, the number of Comptons is definitely a lot larger than the number of photoelectrics.
 
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Astronuc said:
If one looks at the cross-sections of PE and CE, one finds that PE dominates at lower energies. As gamma energy increases, the probability of Compton scattering increases.

Yup. Compton scattering spectroscopy is usually done in the 100 keV range so that's where CS is a strong enough process to produce decent statistical certainty. It's a pretty handy technique to probe certain things. One can map fermi surfaces, probe coordination and bond lengths etc. with CS. It's pretty painful with lab x-ray equipment but at 3rd gen synchrotrons have increased interest in it.
 
  • #10
jtbell said:
That depends of course on the energy of the photon. In one of our undergraduate labs, students send 662-keV gammas from Cs-137 into a NaI scintilator and do a pulse-height analysis of the spectrum that comes out of the scintillator's photodetector. I don't have a spectrum handy here at home, but the numbers of pulses from photoelectric and Compton interactions are in the same general ballpark, with probably more Comptons.

For higher-energy gammas, say the approx. 1.2 MeV ones from Co-60, the number of Comptons is definitely a lot larger than the number of photoelectrics.

This looks exactly the experiment I am doing and is what led me to ask this question while thinking about the theory behind it. A convenient reason why the photoelectric effect occur at lower energy levels is because the incoming photons doesn't have enough energy to give energy to the electron and go off on its own (as in Compton). In this regard, the photoelectric and compton effects are much closer related.

Although as Zapper suggested, the type of atom is also important as to which effect takes place.
 
  • #11
So, which comparison between CS and PE is correct? I am confuse.
 
  • #12
Compton scattering can occur on either free electrons or lightly bound electrons. The defining characteristic is that there is always a recoil photon. For low energies, Compton scattering is sometimes called Thomson scattering. The differential Compton scattering is sometimes referred to as Klein-Nishina scattering. The low energy (classical Thomson) total cross section is about
σ = (8 pi/3) re2 = 0.666 barns, where re is the classical electron radius.
For photon energies over ~0.5 MeV, the Compton cross section drops off due to relativistic effects. It is independent of the nuclear charge Z.
Below ~60 KeV in air (~600 KeV in lead), the dominant photon attenuation cross section is where the photon energy is completely absorbed by a bound electron. For photon energies in the KeV region, this is often referred to as deep core photo-ejection. Very roughly, the cross section is crudely proportional to Z4/Ephoton3. The photo-ejection cross section can suddently jump by an order of magnitude as the photon energy crosses the binding energy (absorption edge) of the K-shell electron (~33 KeV in sodium iodide, ~90 KeV in lead). Complete photon absorption by a bound electron in the visible and UV region is usually called the photoelectric effect or photoionization.
Bob S
 
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  • #13
Why does not this relativistic effect come into account when photoelectric effect takes place?
 

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