With regard to operators, maybe someday mathematicians will get their acts together as well as the people who design programming languages. All of the languages based on C have tables of precedence and associativity, which enables one to unequivocally state how some expression will be evaluated. Although C, C++, C#, and Java don't have an exponentiation operator, Python does have such an operator -- ** -- the same as Fortran uses.
The Python docs say that this operator associates right-to-left, which means that 2 ** 3 ** 3 is the same as if written as 2 ** (3 ** 3). Most of the other operators associate left-to-right. Using a more mathematical notation, this would be ##2^{3^{3}}##, which if evaluated using the Python rules would be the same as if written ##2^{(3^3)}##.
We have PEDMAS, (or BEDMAS/BODMAS, for those who can't distinguish between parentheses, braces, brackets, and angle brackets) which gives the relative precedence of the different categories, with parentheses at the highest level, but this convention doesn't also provide information about how an expression with more than two operands associates, or groups.