The discussion centers on the hydration and hygroscopic nature of crystalline solids, specifically addressing sodium chloride (NaCl) and sodium carbonate decahydrate (Na2CO3.10H2O). It clarifies that not all crystalline solids are hydrated or hygroscopic. Na2CO3.10H2O is a hydrated form of sodium carbonate, while anhydrous sodium carbonate (Na2CO3) can also exist without water. The presence of crystalline water in some substances often results from crystallization from aqueous solutions, making them hygroscopic. However, anhydrous crystals can be produced under specific conditions, and their hygroscopicity is determined by their chemical affinity for water, not solely by their crystalline structure. The example of quartz illustrates that some crystalline materials do not contain water and are not hygroscopic.