You have to simplify one branch at a time where resistors are clearly either in series or parallel. Starting at the left branch, it begins to simplify like so:
[1] Recognize that the two 3Ω resistors are in series, add them: 3Ω + 3Ω = 6Ω. Replace that resistor in next step.
[2] With the new 6Ω resistor in place we now recognize that it is in parallel with the AD 6Ω resistor, so we do the math to simplify them: 6Ω || 6Ω = 3Ω
[3] The 3Ω resistor replaced the previous parallel ones.
With these simplifications we see that the "arm ADE" is actually the equivalent of two 3Ω resistors in series, thus 6Ω.
Also, I don't like how your book uses phrases like "Therefore Effective Resistance between A and E is given by." This is confusing, as it is only one path between points A and E, NOT the equivalent resistance. The true effective resistance between A and E would be when all resistors in the diagram are simplified down to one resistance (with respect to A and E, e.g. when all that remains is one resistor in between point A and point E).
Hope that helps.