Dismiss Notice
Join Physics Forums Today!
The friendliest, high quality science and math community on the planet! Everyone who loves science is here!

Default equilibrium-constant?

  1. Dec 12, 2012 #1
    Let's say we have the reaction 2H2 + O2 -> 2H2O. The equilibrium constant for this reaction then is: K1=[H2O]2]/([H2]2*[O2]).

    But the reaction can also be written as H2 + 0.5O2 -> H2O, and with the equilibrium constant becoming K2 = [H2O]1]/([H2]1*[O2]0.5)=K10.5

    This phenomena with the coefficients goes generally for all reactions. So, what K is the default one? Is it the one where most coefficients are 1 (K2), or is it when all coefficients are at their smallest, while remaining integers (K1)? Or something else?
     
  2. jcsd
  3. Dec 12, 2012 #2

    DrDu

    User Avatar
    Science Advisor

    There is no general default. Usually you have to give the reaction equation along with the equilibrium constant.
     
  4. Dec 12, 2012 #3

    Borek

    User Avatar

    Staff: Mentor

    Most often you will see the equilibrium constant for the properly balanced reaction equation - that is, with all coefficients being the smallest possible integer numbers. So when there is no other information I would assume value given is K1. Serious sources of equilibrium constants usually define the convention used, to make the information unambiguous.

    Which basically boils down to what DrDu wrote earlier.
     
Know someone interested in this topic? Share this thread via Reddit, Google+, Twitter, or Facebook




Similar Discussions: Default equilibrium-constant?
  1. Equilibrium constant (Replies: 8)

  2. Equilibrium constant? (Replies: 1)

  3. Equilibrium constant (Replies: 1)

  4. Equilibrium Constants (Replies: 4)

Loading...