Sophiecentaur, I suppose so, but this seems a very small part of the overall matter of things. Thank you (and the other commenters) for the very good comments that have helped me grasp how mirrors work. I am still hung up on the question of how opaque objects reflect light. If you can bear with me a little longer.
Here is Wikipedia:
- Light arriving at an opaque surface is either reflected "specularly" (that is, in the manner of a mirror), scattered (that is, reflected with diffuse scattering), or absorbed – or some combination of these.
- Opaque objects that do not reflect specularly (which tend to have rough surfaces) have their color determined by which wavelengths of light they scatter strongly (with the light that is not scattered being absorbed). If objects scatter all wavelengths with roughly equal strength, they appear white. If they absorb all wavelengths, they appear black.
- Opaque objects that specularly reflect light of different wavelengths with different efficiencies look like mirrors tinted with colors determined by those differences. An object that reflects some fraction of impinging light and absorbs the rest may look black but also be faintly reflective; examples are black objects coated with layers of enamel or lacquer.
As mentioned earlier, when I read this I take it to mean that any surface will either absorb some or all wavelengths present, or reflect some or all wavelengths. As I understand it, this is due to the photons exciting electrons at either resonant or non-resonant frequencies. Those wavelengths of light that cause electrons in the object's surface to resonate will be converted to thermal energy and are not re-emitted as light. Those that do not cause resonance are re-emitted as light.
When an opaque surface is rough enough, the re-emitted light is emitted in diffuse form, that is at angles determined by the various angles of incidence on the many planes of the surface at the micro-scale.
When an opaque surface is smooth enough however, the re-emitted light is emitted in specular form, that is at the same angle as the angle of incidence. This is because the surface has far fewer planes at the micro-scale, perhaps just one.
But what I am tripping up on is what this means for surface reflectance.
It seems to me that the initial condition of what light can be reflected or absorbed is determined by the composition of the object, not its surface smoothness. An opaque object that reflects blue light wavelengths absorbs other wavelengths - that is, green, red, yellow, etc wavelengths are absorbed and converted to thermal energy. I take this to mean that any object, regardless of surface smoothness, will absorb and reflect according to composition. A smooth blue cube is blue, as is a rough blue cube (bear in mind that I really mean something like that the EMR field sampled at a given point in space by a measuring device pointed at the cube will peak at blue wavelengths for the visible spectrum).
However, as per our discussion, if our cube has a smooth enough surface it will reflect wavelengths other than blue. That is how we can have mirrors and how any smooth enough surface can reflect images of objects that shine on the surface being observed. In that case, the EMR field will be sampled with different peaks for the visible spectrum according to where on the cube's face we point our measuring device.
My best guess at explaining this is that not all non-blue wavelengths are fully absorbed. Other wavelengths are partly absorbed and partly re-emitted according to the cube's composition (ie arrangements of atoms). Thus for a rough surface (ie the case of diffuse reflection) re-emitted non-blue wavelengths are at lower intensity than blue wavelengths (due to part absorption). I guess this might mean they are either scattered more by the rough surface or are scattered at the same "density" as blue wavelengths but affect the measuring device less. In the case of our eyes, the blue wavelengths are intense enough to activate cone cells, but the other wavelengths present are not. For a smooth surface however, the scattering is much less to non-existent and so the non-blue wavelengths achieve sufficient intensity to affect the measuring device noticeably. In the case of our eyes, to activate cone cells. This is why a uniformly blue (or black, for example) surface will not appear uniformly blue or black when it is very smooth.
I think if I boil it all down, where I may have been going wrong is to believe that when sources say light is absorbed or reflected, I took that as an absolute statement. I suspect it is not.
Have I grasped what's going on? If I am way out, I'll leave it there.