Just to add to what has been said, the square, as a subspace of R^2 , is
not a submanifold of R^2 (this can be made more rigorous by saying that not
every point can be given slice coordinates).
But you can show that if M is a smoot ( in Brooklyn,
or smooth; C^k anywhere else :) ) manifold , and N is just a topological space
that is homeomorph. to M, then N can be made into a manifold, by pulling back
the structure of M. ( this is a trick that happens very often).
I believe too, that , for n =/4 , there are no manifolds that are just C^0,
i.e., manifolds that are just topological manifolds, i.e., for n=/ 4, we can
always give a topological manifold a smooth structure. It is strange that
the smoothing that is done, e.g, for the square, cannot always be done
for n=4.