Does the APF depend on the temperature

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Discussion Overview

The discussion centers on whether the atomic packing factor (APF) depends on temperature, exploring its implications across different materials, including metals and ceramics. Participants examine the relationship between APF and changes in crystal structure and lattice parameters due to temperature variations.

Discussion Character

  • Debate/contested

Main Points Raised

  • One participant suggests that the APF may depend on temperature, particularly noting changes in the Bravais lattice for iron.
  • Another participant questions how the APF is defined and whether its characteristics could change with temperature.
  • A participant proposes that since APF is the ratio of the volume of atoms to the volume of the unit cell, changes in lattice structure would likely affect the APF, but they wonder if this applies to all materials or just metals.
  • One participant expresses skepticism about the APF depending on lattice constants but acknowledges that changes in crystal structure can occur in nonmetals as well.
  • A participant raises the issue of thermal expansion and contraction affecting the APF due to temperature changes.
  • Another participant inquires about the APF for hexagonal close-packed structures and whether it is temperature-dependent if the crystal arrangement remains unchanged.

Areas of Agreement / Disagreement

Participants do not reach a consensus on whether the APF depends on temperature, with multiple competing views presented regarding its dependence on material type and structural changes.

Contextual Notes

There are unresolved questions regarding the definitions of APF and how temperature influences various material characteristics, as well as the specific conditions under which changes occur.

Dell
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does the APF depend on the temperature
a) yes
b) no
c) only for metals
d) only for ceramics

i know that for iron for example the bravias lattice can change at different temperatures, but does the atomic packing factor also, i would think yes, but is this true for all materials or just metals?
 
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How is the APF defined? What characteristics of a material does it incorporate? Could these characteristics change slowly (or hint: suddenly) with temperature?
 
i would think so, if it is the volume of the atoms/ volume of the cube, and the lattice changes i would think that the APF would too, but i know this can happen in metals, but is it true for all materials or only metals
 
I don't believe the APF depends on the lattice constant, but I agree that it will change with crystal structure. And yes, crystal structure changes are possible with nonmetals also (e.g., diamond/graphite).
 
how about expansion and contraction due to temperature changes?!
 
Well, what's the APF for a hexagonal close-packed structure, for example? Does it depend on temperature, as long as the crystal arrangement is unchanged?
 

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