Thanks guys, and I appreciate your patience with me!
Consider this hypothetical overly-simplified example.
Let's say an electron can occupy two positions (double well) in a protein, separated by an energy barrier.
A wave function would then describe probability amplitudes of finding the electron in either position (or, rather, BOTH positions). Superposition of the electron in both positions is a necessity of the wave function..?
Since there is an energy barrier separating the double well, then there seemingly would be greater probability of finding the electron in the lower well than the higher energy well... and so, upon observation, the electron could be in either (lower energy, or higher energy via tunneling), however, since there is greater probability the electron will be observed in the lower energy well, then.. would you say- once an observation is made, the electron will be found in the lower energy well "more often than not"?
Again, thanks for your patience.. I'm a life science guy :)