Effect of Dry Salt Bridge on Cell Potential in Galvanic Lab Experiment

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SUMMARY

The discussion centers on the impact of a dry salt bridge, specifically one not wetted with KNO3, on the cell potential in a galvanic lab experiment. It is established that a dry salt bridge prevents ion movement, leading to a decrease in cell potential, resulting in a more negative Ecell value. The inability of ions to migrate across the bridge disrupts the spontaneous reaction necessary for generating electrical potential. Thus, the measured potential of the cell will be significantly affected, confirming the critical role of a wetted salt bridge in galvanic cells.

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  • Understanding of galvanic cells and their components
  • Knowledge of electrochemical potential and Ecell calculations
  • Familiarity with the role of salt bridges in electrochemical cells
  • Basic principles of ion migration and conductivity
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  • Research the role of KNO3 in salt bridges and its impact on ion conductivity
  • Explore the Nernst equation and its application in calculating cell potential
  • Investigate the effects of different electrolytes on galvanic cell performance
  • Learn about experimental setups for measuring cell potential in electrochemistry
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Chemistry students, laboratory technicians, and educators involved in electrochemistry and galvanic cell experiments.

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Homework Statement


What will the affect be on the potential of the cell if salt bridge isn't wetted?
If the salt bridge isn't wetted with KNO3 how would it affect the measured potential of the cell2. The attempt at a solution
So I thought that the potenital will be more negative because since the electrons can not go across the bridge this wouldn't be spontaneous and would have a negative Ecell charge?
 
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disneychannel said:

Homework Statement


What will the affect be on the potential of the cell if salt bridge isn't wetted?
If the salt bridge isn't wetted with KNO3 how would it affect the measured potential of the cell


2. The attempt at a solution
So I thought that the potenital will be more negative because since the electrons can not go across the bridge this wouldn't be spontaneous and would have a negative Ecell charge?

What is the potential of an open circuit?
 
the potential is positive... ***ions not electrons
 

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