Electrolysis using a single electrode

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Discussion Overview

The discussion revolves around the feasibility of performing electrolysis in saltwater using a single electrode. Participants explore theoretical aspects, practical challenges, and different interpretations of electrolysis processes.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant proposes the idea of using a single electrode for electrolysis in saltwater, questioning its theoretical possibility.
  • Another participant agrees that it is theoretically possible but emphasizes the necessity of a second electrode, even if it is not immediately apparent, to allow for charge flow.
  • A different perspective is offered regarding the types of electrolysis, distinguishing between water breakdown into hydrogen and oxygen and the process of plating ions, noting that the latter is easier but may be slow with low current.
  • A participant acknowledges a misunderstanding regarding the need for current to flow through the water, indicating a refinement of their initial approach.

Areas of Agreement / Disagreement

Participants express differing views on the necessity of a second electrode and the feasibility of the proposed method. The discussion remains unresolved regarding the practical implementation of electrolysis with a single electrode.

Contextual Notes

There are limitations regarding the assumptions made about the electrolysis process, particularly the role of the second electrode and the specifics of current flow through the electrolyte.

uzi kiko
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Hello

Inspired by this video,


I wondered if it was possible to create a process of electrolysis in saltwater using a single electrode.
To my understanding (Please see the attached diagram), if a direct current passes through I2 (after the diode) a direct current must also pass through I1 (through the electrode). However, in a small experiment I did, based on this diagram, I was unable to produce electrolysis products

Does this theoretically seem possible to you?

Thanks a lot
Mosh
 

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Theoretically yes, as far as you've described it anyway. But there are a lot of other details to get right. For one, there must always be a 2nd electrode of some sort, although it could be disguised (like a metal tank wall, for example). Charges must flow from somewhere to somewhere else, those would be the electrodes.

Look at some of the "related threads" below. Electrolysis isn't as easy to do as it sounds.
 
I guess I was assuming you wanted to breakdown water into Hydrogen and Oxygen. Of course there is also electrolysis in the sense of plating (moving ions through an electrolyte). That is much easier. For example moving Zinc ions from a Zinc electrode onto a Copper electrode is easy. However, the process may be slow with harvested energy because the current will be low.
 
Thanks a lot!

you're absolutely right. In my experiment, I ignored the need for the current to eventually move through the water ...
 
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