A change in magnetic flux induces an electromotive force (emf) in a wire, as described by Faraday's law, which states that emf is proportional to the rate of change of flux. When a wire moves through a magnetic field, free electrons experience a Lorentz force, causing them to accumulate at one end of the wire, creating a potential difference. This process can be analyzed using both the formula for motional emf (emf = BLv) and the change in magnetic flux over time. The discussion highlights that the induced emf can occur even in a non-uniform magnetic field and emphasizes the importance of defining a closed path for calculating emf. Ultimately, the interaction between the wire and the magnetic field leads to the establishment of an electric field that maintains charge separation, resulting in induced emf.