Enthalpy of Combustion: Definition & Reactions

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The discussion centers on the definitions of enthalpy related to combustion reactions. Two definitions are presented: one defines enthalpy as the heat change when one mole of a substance is completely burned or oxidized, while the other specifies it as the heat change when one mole of a compound is burned or oxidized in oxygen. The inquiry arises regarding the applicability of the second definition to reactions involving elements, such as hydrogen and carbon, which are not compounds. The consensus suggests that both definitions could be clarified to include "substance or compound" to encompass all scenarios, including elemental reactions.
Hydrous Caperilla
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I got two definitions for this enthalpy:

I)Heat change when 1 mole of a substance is completely burned or oxidised(My textbook)
2) Heat change when 1 mole of compound is completely burnt or oxidized in oxygen(From a site)

So if I had this reaction:

H2(g)+1/2 O2(g)---->H20

C(s)+O2(g)------>CO2

How can definition number 2 work for these reactions where there is no compounds.
 
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Hydrous Caperilla said:
I got two definitions for this enthalpy:

I)Heat change when 1 mole of a substance is completely burned or oxidised(My textbook)
2) Heat change when 1 mole of compound is completely burnt or oxidized in oxygen(From a site)

So if I had this reaction:

H2(g)+1/2 O2(g)---->H20

C(s)+O2(g)------>CO2

How can definition number 2 work for these reactions where there is no compounds.
In either definition, they could have worded it "when 1 mole of a substance or compound...".
 
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