Equilibrium Question: Can Anyone Help?

  • Thread starter Thread starter mister_mister3
  • Start date Start date
  • Tags Tags
    Equilibrium
AI Thread Summary
The discussion revolves around a question regarding a system at equilibrium containing benzene, iodine, and air at 298K. The key points include the evaluation of four statements about the system. The original poster expresses confusion, believing all statements to be false: the vapor pressure should remain constant unless temperature changes, evaporation should cease at equilibrium, the liquid's color should not change without external factors, and the mass of solid iodine should remain constant at saturation. After further reflection, the poster concludes that statement B, which suggests that evaporation continues at equilibrium, is indeed true, as evaporation and condensation occur at equal rates. This realization highlights the need for deeper understanding of equilibrium dynamics.
mister_mister3
Messages
7
Reaction score
0
A simple question, it would seem, but I'm missing something..
This is a question in my text.

Q: Consider a stoppered flask containing benzene, iodine, and air, which has reached equilibrium at 298K. Which one of the following statements concerning the system at equilibrium is true?

a) The pressure of the vapour phase is not constant.
b) Evaporation of the liquid continues.
c) The colour of the liquid phase will change.
d) The mass of the solid iodine is not constant.

A: I haven't yet had my text throw me a curveball, but I have found numerous errors which I've confirmed with administrators of the course I'm taking. This one stumps me, which makes me think there's an error. For this one, they all seem untrue. for a), I would think that the pressue of the vapour phase would stay constant unless there were a change in temp. for b) at equilibrium, would evaporation not cease? c) the colour of the liquid will change - obviously not true, since there would have to be a change in temp, or pressure and for d) the iodine would have reached a point of saturation in the benzene at equilibrium, so that couldn't change either...

Can anyone point out what I'm missing? Any help is greatly appreciated!
 
Chemistry news on Phys.org
Write out the balanced equation
 
mister_mister3 said:
A simple question, it would seem, but I'm missing something..
This is a question in my text.

Q: Consider a stoppered flask containing benzene, iodine, and air, which has reached equilibrium at 298K. Which one of the following statements concerning the system at equilibrium is true?

a) The pressure of the vapour phase is not constant.
b) Evaporation of the liquid continues.
c) The colour of the liquid phase will change.
d) The mass of the solid iodine is not constant.

A: I haven't yet had my text throw me a curveball, but I have found numerous errors which I've confirmed with administrators of the course I'm taking. This one stumps me, which makes me think there's an error. For this one, they all seem untrue. for a), I would think that the pressue of the vapour phase would stay constant unless there were a change in temp. for b) at equilibrium, would evaporation not cease? c) the colour of the liquid will change - obviously not true, since there would have to be a change in temp, or pressure and for d) the iodine would have reached a point of saturation in the benzene at equilibrium, so that couldn't change either...

Can anyone point out what I'm missing? Any help is greatly appreciated!

my guess is that B is the only one that is true. at equilibrium, the liquid will keep evaporating and condensing in the container, and the rates of both will be equal.
 
agreed

Thanks,

after spending more time examining the situation, I came to the same conclusion myself. It just required some more thought I suppose.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
Back
Top