Determining Exposure Times for Spectrographic Film

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SUMMARY

This discussion focuses on determining exposure times for spectrographic film when capturing spectra of lithium, carbon, and mercury using a spectrograph. The exposure time is influenced by factors such as the radiance of the light source, the f-number of the optical system, and the ISO film speed. Specifically, when using an electric arc as the light source, the alignment of electrodes, the amount of lithium, and the stability of the arc significantly affect exposure times. Experimentation is necessary to find optimal exposure times to capture both strong and weak spectral features effectively.

PREREQUISITES
  • Understanding of spectrograph operation and principles
  • Knowledge of exposure time calculations in photography
  • Familiarity with light source characteristics, particularly electric arcs
  • Basic concepts of film sensitivity (ISO) and dynamic range
NEXT STEPS
  • Research methods for calculating exposure times based on irradiance and energy density
  • Explore the use of digital cameras or CCD arrays for spectrographic applications
  • Study the impact of f-number on exposure and image quality
  • Investigate techniques for optimizing light source stability and alignment
USEFUL FOR

Researchers, photographers, and scientists involved in spectroscopy, particularly those working with film-based methods and seeking to optimize exposure times for accurate spectral analysis.

spaghetti3451
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I am taking the spectra of lithium, carbon and mercury on a piece of film with the help of a spectrograph. One of the parameters that affect the readings is the exposure times. (How?) I have to find the correct exposure times experimentally. (Why?) That is because the exposure times depend on the quality of the source. (So what?) For instance, if a lithium spectrum is taken using an electric arc as the source (the electric arc is produced by two lithium-doped carbon electrodes), then the exposure times depends on the alignment of the electrodes, the amount of lithium used and the stability of the arc. (So how does that influence the exposure time?).

So, I have to take several spectra using different exposure times to properly expose both the strong and weak features. (Don't get this point.)

Any help would be greatly appreciated.
 
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failexam said:
I am taking the spectra of lithium, carbon and mercury on a piece of film with the help of a spectrograph. One of the parameters that affect the readings is the exposure times. (How?)
Flim exposure depends on the total accumulated energy density at the film plane, thus it is the product of irradiance (watts/meter^2) at the film plane and the exposure time. Longer exposure times allow more light energy to hit the film.
failexam said:
I have to find the correct exposure times experimentally. (Why?)
Likely because you don't know the radiance (watts/[steradian*meter^2]) of the source, f-number of the optical system, and the sensitivity (ISO film speed) of the film.
failexam said:
That is because the exposure times depend on the quality of the source. (So what?)
The quality of the source effects it's radiance.
failexam said:
For instance, if a lithium spectrum is taken using an electric arc as the source (the electric arc is produced by two lithium-doped carbon electrodes), then the exposure times depends on the alignment of the electrodes, the amount of lithium used and the stability of the arc. (So how does that influence the exposure time?).
A source with higher radiance (e.g. brighter) requires less exposure time to get the same amount of energy density at the film plane.
failexam said:
So, I have to take several spectra using different exposure times to properly expose both the strong and weak features. (Don't get this point.)
Typical film has a dynamic range of about 8 stops (2^8=256). That means the ratio of the engeries of the brightest and dimest features can be no bigger than 256.
failexam said:
Any help would be greatly appreciated.
It looks like you have to determine exposure time experimentally.

Have you considered using a digital camera or CCD array? With a digital camera, you see the results quickly without having to run off to the darkroom. Also, you might find a digital camera or CCD with a higher dynamic range than film.
 
Thanks!
 

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