Finding Activation Energy From Arrhenius Plot

In summary, the task at hand is to find the activation energy of an experiment by creating an Arrhenius plot and using the half-life time of the reaction at different temperatures. The relevant equations are the temperature (K), ln k, and 1/T values. The initial attempt is to plot ln k vs 1/T, but there is a question about the concentration of H2O being ignored in the rate law reaction. It would only be ignored if the rate of the reaction is not affected by the concentration of H2O.
  • #1
BayernBlues
65
0

Homework Statement



For a lab, I need to find the activation energy of an experiment from plotting the Arrhenius plot. I have the half-life time of the reaction at various temperatures.

Homework Equations



-Temperature (K)
318
322
327
331
338

-ln k
-6.17
-5.89
-5.65
-5.33
-5.01

-1/T
3.145 x 10^-3
3.106 x 10^-3
3.058 x 10^-3
3.021 x 10^-3
2.956 x 10^-3

The Attempt at a Solution



So far I've plotted ln k vs 1/T.
 
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  • #2
Ok forget that. why would the concentration of H2O be ignored in a rate law reaction?
 
Last edited:
  • #3
It would be ignored if the rate of the reaction was independent of H2O concentration.
 
  • #4
Because it is a (l) and we only consider the concentrations of (aq) solutions.
 

What is activation energy?

Activation energy is the minimum amount of energy required for a chemical reaction to occur. It is a barrier that must be overcome for reactant molecules to form products.

What is an Arrhenius plot?

An Arrhenius plot is a graph that shows the relationship between the rate of a chemical reaction and the temperature at which the reaction occurs. It is named after Swedish chemist Svante Arrhenius who first proposed the concept.

How do you find activation energy from an Arrhenius plot?

To find activation energy from an Arrhenius plot, you need to plot the natural logarithm of the rate constant (ln k) against the reciprocal of temperature (1/T). The slope of the resulting line is equal to -Ea/R, where Ea is the activation energy and R is the gas constant. Therefore, multiplying the slope by -R will give you the activation energy in units of joules per mole (J/mol).

What is the significance of finding activation energy from an Arrhenius plot?

Finding activation energy from an Arrhenius plot can provide valuable information about the nature of a chemical reaction. It can help determine the mechanism of the reaction, the stability of the reactants and products, and can even suggest potential ways to speed up or slow down the reaction.

What are some possible sources of error when finding activation energy from an Arrhenius plot?

Some possible sources of error when finding activation energy from an Arrhenius plot include experimental errors such as imprecise measurements, errors in temperature readings, and variations in experimental conditions. Additionally, assumptions made in the calculation, such as assuming a constant value for the rate constant, can also lead to errors.

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