Finding chemical potential with given thermodynamic relation

In summary, to find the chemical potential μ(T,P) for a given relation among entropy, volume, internal energy, and number of particles, you can express p and T in terms of U, S, and V, and then set up the Gibbs free energy function G(T,p,N)=U-TS+pV to calculate μ from G.
  • #1
Mayan Fung
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Homework Statement


Suppose you are given the following relation among the entropy S, volume V , internal energy U, and number of particles N of a thermodynamic system, where A is a constant.:
$$ S = A(NVU)^{\frac 1 3} $$
Find the chemical potential μ(T,P)

Homework Equations


$$ \frac μ T = -(\frac{∂S}{∂N})_{U,V} $$
U = TS - PV + μN

The Attempt at a Solution


$$ \frac μ T = -(\frac{∂S}{∂N})_{U,V} = \frac 1 3 A N^{-\frac 2 3} (VU)^{\frac 1 3} $$
This only solved μ(U,V,N)
Since internal energy is a function of N,V,T : U(N,V,T)
$$ ∴ μ(U,V,N) → μ(T,\frac V N) → μ(T,P) $$
However, I don't know how to carry out the above transform in this case. I don't know U(N,V,T)

Thanks!
 
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  • #2
Try to express p and T in terms of U, S and V, using dU=TdS-pdV.
Then set up G(T,p,N)=U-TS+pV.
Calculate mu from G.
 
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Likes Mayan Fung
  • #3
Oh! Thanks, I didn't think of that before
 

1. What is chemical potential?

Chemical potential is a measure of the free energy per particle in a thermodynamic system. It represents the potential energy of a substance to undergo a chemical reaction or change in state.

2. How is chemical potential related to thermodynamics?

Chemical potential is one of the fundamental quantities in thermodynamics and is used to describe the behavior of a system in equilibrium. It is related to other thermodynamic variables, such as temperature, pressure, and volume through various thermodynamic relations.

3. What is the significance of finding chemical potential with a given thermodynamic relation?

Finding chemical potential with a given thermodynamic relation allows us to understand the behavior of a system at equilibrium and predict how it will respond to changes in external conditions. It also helps in understanding the energy transfer and transformations within the system.

4. How can chemical potential be calculated?

Chemical potential can be calculated using various thermodynamic relations, such as the Gibbs-Duhem equation, the Maxwell relations, or the Clapeyron equation. The specific relation used depends on the system and the variables that are known.

5. What are some applications of finding chemical potential with given thermodynamic relation?

The knowledge of chemical potential and its relation to other thermodynamic variables is crucial in various fields, such as chemical engineering, material science, and environmental science. It is used to design and optimize processes, understand the behavior of materials, and predict the behavior of chemical reactions.

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