To find the kinetic energy of an electron with a de Broglie wavelength equal to that of a 100 keV x-ray, first calculate the momentum of the photon using p = E/c, where E is the energy in Joules. The de Broglie wavelength can be applied to both electrons and photons, but the momentum for an electron is determined by p = mv. Since the electron shares the same wavelength as the photon, it will have the same momentum. Finally, the kinetic energy of the electron can be calculated using the formula 0.5p^2/m, where m is the mass of the electron.