Finding the eigen function for an infinite square well (quantum mechanics)

AI Thread Summary
The discussion revolves around calculating the wavelength and energy of a photon emitted during a transition of a proton in an infinite square well from the first excited state (n=2) to the ground state (n=1). The participant is attempting to apply the time-independent Schrödinger equation but is confused about the eigenfunctions and boundary conditions. They recognize that the wavefunction must vanish at the boundaries of the well, which imposes restrictions on the possible values of k. The participant is also uncertain about the connection between the well's length and the quantum states. Overall, the thread highlights the complexities of quantum mechanics and the challenges in solving related problems.
ElijahRockers
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Homework Statement



Quantum mechanics is absolutely confusing me.

A proton is confined in an infinite square well of length 10-5nm.

Calculate the wavelength and energy associated with the photon that is emitted when the proton undergoes a transition from the first excited state (n=2) to the ground state (n=1).

In what region of the electromagnetic spectrum does this wavelength belong?

The Attempt at a Solution



I'm not really sure what I'm doing at all.

But I started with the time independent Schrodinger equation. For region I and III, (where the potential is infinite) then the eigenfunction must be 0.

So I put in a potential of zero for the second region and got

\frac{d^2\psi}{dx^2} + k^2\psi = 0 where k^2 = \frac{2mE}{\hbar}

Looks like a second order diff eq, so I tried to solve it. Solutions to the characteristic equation were ±ik...

From here I am a little stumped, I didn't take notes, and I can't remember what the solution was that he used in class.

But anyway if I'm just going by my normal diff eq understanding,

\psi = Acos(kx)+Bsin(kx)

What's throwing me off is that I recall he had exponential solutions with imaginary components in them. These would oscillate, and so does my solution, but even if I had my solution in his form, what next?

Where does the length of the well come into play? What does n=2 -> n=1 mean?
Am I making this more complicated than it should be?
 
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