What Determines the Strength of Forces Between Particles?

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The discussion centers on the classification of intermolecular forces and their relationship to molar mass, polarity, and surface area. It is clarified that these three characteristics alone do not adequately determine the strength of forces between particles. Instead, the focus should be on the types of intermolecular forces: Van der Waals, Dipole-Dipole, and Hydrogen bonding. Substances with hydrogen bonds are generally stronger than those with dipole-dipole or Van der Waals forces. When comparing substances like KBr and SO3, the strength of intermolecular forces is primarily influenced by the type of bond present and, if they are similar, by the molecular mass and surface area. Thus, while KBr may have stronger forces due to its hydrogen bonding and greater molar mass, the classification of forces should be based on the bond types rather than solely on molar mass or polarity.
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Is it true that the Forces between particles determined as follows:
1)Molar mass
2)Polarity
3)Surface area
?


like if i have KBr and SO3 i know that the Forces between particles in KBr is much stronger.
Because KBr have more Molar mass then SO3 and more Polarity.

am i Right?

thnaks.
 
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Forces between particles cannot really be classified by those 3 characteristics you have written. It is best thinking of it in terms of the 3 main forces, Van der Waals, Dipole-Dipole and Hydrogen bonding. In general stuff with hydrogen bonds (0-H,N-H,F-H) will have stronger forces between the molecules than substances with either of the two forces, Van der Waals being the weakest. If you want to compare intermolecular force strength, your best bet is to see which has the storngest type of bond, and if they have the same type of bond, which has the most. If nether is hydrogen or dipole-dipole bonded, then yes, the one with the greatest molecular mass (and hence, usually, surface area) will have the strongest intermolecular forces.
 
thnaks for answer.
 
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