Free electron model (Sommerfeld model)

In summary, using the free electron model, the number of electron quantum states per unit volume in an energy interval of sodium from ##\varepsilon_F## to ##\varepsilon_F + \Delta \varepsilon## is given by ##N=2V \cdot \frac{2 \pi}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} dE##, where ##\Delta \varepsilon## is the energy band width, ##\varepsilon_F## is the Fermi energy of sodium, and ##V## is the unit volume. This equation does not require integration and can be directly calculated by approximating ##dE## as
  • #1
steroidjunkie
18
1

Homework Statement



Using free electron model find the number of electron quantum states per unit volume in ##[\varepsilon_F, \varepsilon_F + \Delta \varepsilon]## energy interval of sodium. Fermi energy of sodium is ##\varepsilon_F = 3.22 eV##, and energy band width is ##\Delta \varepsilon=0.02 eV##.

Homework Equations



##N=2V \cdot \frac{2 \pi}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} dE## - number of electrons in ##[\varepsilon_F, \varepsilon_F + \Delta \varepsilon]##
##E_{TOT}=\int_{\varepsilon_F}^{\varepsilon_F + \Delta \varepsilon} \frac{4 \pi V}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} E dE##

The Attempt at a Solution


[/B]
##E_{TOT}=\frac{4 \pi V 2m^{\frac{3}{2}}}{h^3} \cdot \frac{2}{5}( E_{F+\Delta \varepsilon}^{\frac{5}{2}} - E_{F}^{\frac{5}{2}})##
##E_{TOT}=
\frac{4 \pi V 2m^{\frac{3}{2}}}{h^3} \cdot \frac{2}{5}(3.24^{\frac{5}{2}} - 3.22^{\frac{5}{2}})##
##E_{TOT}=
\frac{4 \pi V 2m^{\frac{3}{2}}}{h^3} \cdot 0.12##

I don't know if this makes any sense so some input would be great.
 
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  • #2
Note that the question asks for the number of electron states that have energies between ##\varepsilon_F## and ##\varepsilon_F + \Delta \varepsilon## for a unit volume of sodium assuming the free electron model. It does not ask for ##E_{TOT}## for this energy range.
steroidjunkie said:
##N=2V \cdot \frac{2 \pi}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} dE## - number of electrons in ##[\varepsilon_F, \varepsilon_F + \Delta \varepsilon]##
This equation will give you the answer directly if you consider ##\Delta \varepsilon## to be small enough that you can approximate ##dE## as ##\Delta \varepsilon##. No integration is needed.
 
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1. What is the Free Electron Model?

The Free Electron Model, also known as the Sommerfeld model, is a theoretical model used to describe the behavior of electrons in a metal. It assumes that the electrons in the metal are free to move and are not bound to any specific atom or nucleus.

2. How does the Free Electron Model explain the properties of metals?

The Free Electron Model explains several properties of metals, such as electrical conductivity and thermal conductivity, by considering the movement of free electrons. These free electrons are able to move freely throughout the metal and are responsible for the flow of electricity and heat.

3. What is the significance of the Fermi energy in the Free Electron Model?

The Fermi energy is the highest energy level occupied by electrons at absolute zero temperature in a metal. In the Free Electron Model, it represents the energy level at which the electrons have the highest probability of being found. It also plays a crucial role in determining the electronic and thermal properties of metals.

4. What are the limitations of the Free Electron Model?

The Free Electron Model is a simplified model and does not take into account the interactions between electrons and the lattice of the metal. It also does not explain the existence of energy bands in metals. Therefore, it is not applicable to all metals and cannot fully explain all their properties.

5. How does the Free Electron Model relate to the band theory of solids?

The Free Electron Model is a precursor to the band theory of solids, which takes into account the interactions between electrons and the lattice of the metal. The band theory explains the existence of energy bands in metals and provides a more accurate description of their properties. The Free Electron Model can be seen as a simplified version of the band theory, with the assumption of free electrons being the main difference between the two models.

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