Free electrons at zero kelvin?

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At zero kelvin, free electrons theoretically have zero energy, yet they can still move under an electric field. This movement raises questions about their kinetic energy when attracted to a positive potential. The discussion clarifies that if electrons are influenced by a potential, they cannot be considered free. In a metal, conduction electrons exist in the conduction band at zero kelvin, allowing them to move freely despite the low temperature. The concept of free electrons at absolute zero is nuanced, as they can still exhibit motion without contributing to temperature.
chewchun
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At zero kelvin,are there free electrons?

At zero kelvin,the free electrons should have ZERO energy.But they are able to move under the influence of a electric field?
But when they are attracted towards the positive potential shouldn't they gain K.E? So they are moving at zero kelvin?
 
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you cannot send fermions at such temperature (they won't ever reach 0 K), just because they are fermions and must obey Pauli's exclusion principle they will have energy from that...
 
Zero temperature just means that all particles reach the lowest-possible states. In terms of fermions, they still have energy compared to the ground-state, but this energy does not contribute to temperature.
Note that this definition does not include any "velocity". You can have a collection of electrons at (close to) zero temperature, moving in one direction in your lab.
 
chewchun said:
At zero kelvin,are there free electrons?

At zero kelvin,the free electrons should have ZERO energy.But they are able to move under the influence of a electric field?
But when they are attracted towards the positive potential shouldn't they gain K.E? So they are moving at zero kelvin?

I do not understand your issue here. By definition, free electrons as ... FREE! If they are attracted to a "positive potential", then they are NOT free electrons in the first place!

So are they free, or aren't they? And where are these "free electrons" that you are considering? A metal? A metal's band structure is often calculated at 0 K! So the conduction electrons are in the conduction band at 0 K! They are free to move!

Zz.
 
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