How Many Quantum States Can Four Bosons Have in a Harmonic Oscillator?

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SUMMARY

The discussion focuses on determining the number of quantum states for four indistinguishable bosons in a one-dimensional harmonic oscillator with a total energy of E_tot = 8 ħω. After distributing the energy quanta, it is established that there are 9 distinct quantum states. The incorrect application of the formula for distinguishable particles is highlighted, leading to confusion. The correct approach involves using the partition function p(M) for indistinguishable quanta, particularly when the number of bosons is greater than or equal to the number of quanta.

PREREQUISITES
  • Understanding of quantum mechanics, specifically bosons and harmonic oscillators.
  • Familiarity with the concept of indistinguishable particles in statistical mechanics.
  • Knowledge of energy quantization in quantum systems, particularly E_n = (n + 1/2)ħω.
  • Basic understanding of partition functions in combinatorial mathematics.
NEXT STEPS
  • Study the partition function p(M) for indistinguishable objects.
  • Learn about the statistical mechanics of bosons and their energy distributions.
  • Explore combinatorial methods for counting indistinguishable particles in quantum systems.
  • Investigate the implications of indistinguishability in quantum statistics and thermodynamics.
USEFUL FOR

Physicists, quantum mechanics students, and researchers in statistical mechanics who are interested in the behavior of bosons in quantum systems.

ghotra
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Suppose I have 4 bosons in a one-dimensional harmonic oscillator potential and that the total energy is E_\text{tot} = 8 \hbar \omega. Recall, E_n = (n+1/2)\hbar\omega.

Question: How many quantum states exist? (assume no spin degeneracy)

After accounting for the ground state, we have 6 quanta of energy to distribute. The harmonic oscillators are indistinguishable, so we do not care about the ordering. Here is my count:

(6,0,0,0)
(5,1,0,0)
(4,2,0,0)
(4,1,1,0)
(3,3,0,0)
(3,2,1,0)
(3,1,1,1)
(2,2,2,0)
(2,2,1,1)

where, for example, (5,1,0,0) means we give one boson 5 quanta and another boson 1 quanta...the other two bosons are in the ground state.

So, there are 9 possible quantum states.

My question: What is the general formula that determines the number of quantum states?

Typical answer:

This situation is akin to have 6 balls and 4-1 walls, and then asking how many ways can you permute those objects. To which, the answer is:

<br /> \binom{6+(4-1)}{4-1} = \frac{[6+(4-1)]!}{(4-1)!6!} = 84<br />

and is _clearly_ wrong. This formula comes from the question of asking how many ways can you put N indistinguishable bosons into d distinguishable degenerate energy levels. Essentially, it cares about the order. That is,

(6,0,0,0) 4!/3! permutations
(5,1,0,0) 4!/2! permutations
(4,2,0,0) 4!/2! permutations
(4,1,1,0) 4!/2! permutations
(3,3,0,0) 4!/2!/2! permutations
(3,2,1,0) 4! permutations
(3,1,1,1) 4!/3! permutations
(2,2,2,0) 4!/3! permutations
(2,2,1,1) 4!/2!/2! permutations

(yes that adds to 84)

For this problem, we are asking: How many ways can you put 6 indistinguishable quanta into 4 indistinguishable bosons? So the questions are not the same and the above formula does not apply. Here is my question once again:

How many ways can we divide M indistinquishable quanta into N indistinguishable bosons?

Notice, if N >= M, then the answer is given by p(M), the partition function of M.
http://en.wikipedia.org/wiki/Integer_partition
 
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