Fredrik said:
If we define "observable" to mean "bounded self-adjoint operator", then of course every hermitian operator is an observable. We defined them to be. There is however another approach. We define our "observables" operationally, by describing the devices that are supposed to measure them. The question is then, what sort of mathematical object should we use to
represent observables mathematically? This sort of thing is discussed in detail in books on the mathematics of QM, e.g. "
An introduction to the mathematical structure of quantum mechanics", by F. Strocchi, and "
Mathematical theory of quantum fields" by H. Araki.
I don't know this stuff myself, but I get that the basic idea is to start with a C*-algebra, define a "state" as a positive linear functional on the C*-algebra of observables, and then invoke the appropriate mathematical theorems to prove that abelian C*-algebras give us classical theories and non-abelian C*-algebras give us quantum theories. (The C*-algebra is then isomorphic to the algebra of bounded self-adjoint operators on a complex separable Hilbert space).
In this approach, it's
not the case that every member of the C*-algebra corresponds to a measuring device, but I don't really have any more information on that. Perhaps someone can read those books and tell the rest of us.
Here's an excerpt from Neumaier & Westra (quant-ph/08101019) that might
give insight into the algebraic approach from a different perspective.
(This is from the start of section 5.1.)
Any fundamental description of physical systems must give account of
the numerical values of quantities observable in experiments when the
system under consideration is in a specified state. Moreover, the form
and meaning of states, and of what is observable in principle, must be
clearly defined. We consider an axiomatic conceptual foundation on the
basis of quantities and their values, consistent with the conventions
adopted by the International System of Units (SI) [238], who declare:
"A quantity in the general sense is a property ascribed to
phenomena, bodies, or substances that can be quantified for, or
assigned to, a particular phenomenon, body, or substance. [...] The
value of a physical quantity is the quantitative expression of a
particular physical quantity as the product of a number and a unit, the
number being its numerical value."
They also have a footnote:
We deliberately avoid the notion of observables, since it is not clear
on a fundamental level what it means to observe something, and since
many things (such as the fine structure constant, neutrino masses,
decay rates, scattering cross sections) which can be observed in nature
are only indirectly related to what is traditionally called an
observable in quantum mechanics. [...]
IMHO, adherence to the SI term "quantity" fosters clearer thinking
about this stuff.
They go on to give a set of axioms for algebras of quantities, and
define states as linear mappings from a space of quantities to a space
of ordinary numbers. This is the basic idea of the algebraic approach.
Any class of physical systems is defined by specifying an algebra of
quantities.
As to whether any element of the algebra can be measured... that gets
tricky. Consider angular momentum J_i. To measure the "pose"
of a system relative to that of another system from the same class we
must the consider the rotation group, which is generated by angular
momentum. Although (\theta^i J_i)^2, (\theta^i J_i)^3 might be hard to imagine
measuring, we have no trouble imagining a finite rotation given by \exp(i\theta^i J_i).
In the rest of the section 5, Neumaier & Westra go on to explain how
their axioms encompass both classical and quantum systems (including
thermodynamics/statistics). The algebraic approach thus unifies
all of physics under a more coherent umbrella. In section 5.4, they
discuss limits of experimental resolution and uncertainty, and show
how the essential difference between "classical" and "quantum" boils
down to commutativity of quantities.
Ordinary Hilbert spaces become merely a convenience, appropriate to
certain cases, on which the quantity algebra can be represented as
operators.
HTH.