How Can I Safely Utilize Freshly-Isolated Silicon?

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Discussion Overview

The discussion revolves around the potential uses of freshly-isolated silicon, particularly in the context of water filtration and the production of silicone. Participants explore various experimental approaches and safety considerations related to handling silicon and its chemical reactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant inquires about the uses of freshly-isolated silicon, mentioning its potential for water filtration and the possibility of making silicone.
  • Another participant questions whether the silicon is pure or if it is silicon oxide, suggesting checking its semiconductor properties by observing resistance changes with heat.
  • Some participants discuss the isolation process of silicon from silica using magnesium and muriatic acid, detailing the chemical reactions involved.
  • Concerns are raised about the safety of handling magnesium and silane gas, with warnings about the dangers of pyrophoric materials and the need for proper safety precautions.
  • A participant acknowledges the risks involved in the isolation process and expresses interest in the production of silane gas while agreeing on the importance of safety measures.
  • Corrections are made regarding the chemical equations presented, with one participant clarifying the products of reactions involving magnesium and hydrochloric acid.
  • Another participant expresses doubt about the safety and feasibility of the proposed methods, suggesting that the original poster may lack the necessary knowledge to conduct the experiments safely.

Areas of Agreement / Disagreement

Participants express a range of views on the safety and feasibility of isolating silicon and producing silane gas. There is no consensus on the practicality of the proposed methods, and significant concern is raised about the risks involved.

Contextual Notes

The discussion highlights limitations in the participants' understanding of chemical reactions and safety protocols, as well as the potential hazards associated with the isolation and handling of silicon and its compounds.

Theoden
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Let's say I have an amount of freshly-isolated silicon in the bottom of a jar of water. I have heard it is usable for water filtration; but how else could I use this element, and with it could I make silicone? I have searched google on making silicone, but all I have found are subjects about things like caulking.
Any help would be greatly appreciated!
 
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Is this just for jun? A project or experiment?
 
I suppose this would be an experiment.
 
So you just have some piece of silicon (is it really pure silicon, or silicon oxide, doped or something else?) and you don't know what to do with it?

You could check if it really behaves like a semiconductor, e. g. decreases its resistance when heated.
 
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mfb said:
You could check if it really behaves like a semiconductor, e. g. decreases its resistance when heated.
That's a good one. I was going to say that, but you beat me to it :)

I would also say build yourself a solar cell, but that's not plausible.
 
Theoden said:
Let's say I have an amount of freshly-isolated silicon in the bottom of a jar of water. I have heard it is usable for water filtration; but how else could I use this element, and with it could I make silicone? I have searched google on making silicone, but all I have found are subjects about things like caulking.
Any help would be greatly appreciated!
Well, sand (SiO2) is used in water filtration commonly, but I've never heard of elemental silicon being used in that fashion.
 
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Theoden said:
Let's say I have an amount of freshly-isolated silicon in the bottom of a jar of water.
Are you sure you mean to say silicon and not silica? How exactly do you precipitate elemental silicon in water?
 
Thanks everyone!

The isolation recipe involves mixing silica with magnesium and heating it ( to separate it into layers: magnesium, magnesium oxide, magnesium silicide, and purified silicon at the bottom ), then dropping it in in a diluted form of muriatic acid ( to get everything but the purified silicon out of the solution ). The skeleton equations would be something like this:
12Mg + HCl --> 12Mg + H + Cl
Si + HCI --> SiH4 + Cl
 
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Theoden said:
The isolation recipe involves mixing silica with magnesium and heating it ( to separate it into layers: magnesium, magnesium oxide, magnesium silicide, and purified silicon at the bottom ), then dropping it in in a diluted form of muriatic acid ( to get everything but the purified silicon out of the solution ). The skeleton equations would be something like this:
12Mg + HCl --> 12Mg + H + Cl
Si + HCI --> SiH4 + Cl

1) Heating magnesium metal and working with silane gas are both very dangerous propositions, even for someone who knows what they're doing (see point 2).
2) Your equations make no sense. "H" and "Cl" by themselves are not species that appear in chemical reactions like this. Also, combining magnesium with HCl will give you hydrogen gas and MgCl2. Combining silicon with HCl will probably give you silicon tetrachloride, or at best a mixed silicon hydrochloride.
3) Even if you do manage to prepare silane gas, it is immediately pyrophoric (catches fire spontaneously) in air.

I think what you're trying to do here is to thermally decompose silane derived from magnesium silicide. Given the level of chemistry knowledge demonstrated in your other posts on this thread, I can't in good conscience recommend you do this on your own.
 
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  • #10
TeethWhitener said:
1) Heating magnesium metal and working with silane gas are both very dangerous propositions, even for someone who knows what they're doing (see point 2).
2) Your equations make no sense. "H" and "Cl" by themselves are not species that appear in chemical reactions like this. Also, combining magnesium with HCl will give you hydrogen gas and MgCl2. Combining silicon with HCl will probably give you silicon tetrachloride, or at best a mixed silicon hydrochloride.
3) Even if you do manage to prepare silane gas, it is immediately pyrophoric (catches fire spontaneously) in air.

I think what you're trying to do here is to thermally decompose silane derived from magnesium silicide. Given the level of chemistry knowledge demonstrated in your other posts on this thread, I can't in good conscience recommend you do this on your own.

I'd have to admit, this process is very dangerous; and must be done under a fume hood, perhaps with a gas mask, and possibly behind a blast sheild. Thank you for your concern! I will continue to take precautions when preforming. I personally think the production of silane gas is the most interesting aspect of the process; but I agree, It should also be done outside or in a fume hood.
I did not know magnesium and chlorine combined. Thanks for pointing that out! I knew something was wrong with my equation, but I couldn't figure the problem out until you mentioned it.
I assume this would be the fixed version:
12Mg + HCl --> MgCl2 + H

Thanks again!
 
  • #11
It is dangerous even if you do it with all those precautions. And where is the point? You don't have the knowledge to do it safely, and we won't help to hurt yourself here. Thread closed.
 

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