How do covalent bonds of the same molecule form?

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SUMMARY

Covalent bonds form when atoms share electrons, resulting in a configuration with higher binding energy compared to configurations without shared electrons. In the case of carbon (C-C), both atoms seek to complete their valence shells by sharing four electrons, despite having no difference in electronegativity. This sharing occurs because each carbon atom has an incomplete shell, allowing the electrons of one atom to approach the nucleus of the other. Additionally, the promotion of 2s to 2p orbitals enhances this bonding effect.

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  • Familiarity with quantum mechanics principles
  • Awareness of Pauli exclusion principle and van der Waals forces
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Kuzon
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There is no difference in electronegativity, so how do bonds form?

Take for example C-C, they both want 4 electrons for a full valence shell to become more stable - they meet each other, but how come they share 4 electrons? There is no difference in electronegativity for them to attract each other.

Also - can atoms only bond to themselves when they have half a valence shell full of electrons? E.g. carbon can bond to itself because it has 4 valence electrons but also needs 4 so another carbon fills its valence shell perfectly.Apologies if any parts of my question confuse you, I just started chemistry so I don't have a solid grasp on these concepts.
 
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Covalent bonds form when atoms share electrons ... physically the configuration with the shared electrons has a higher binding energy than the configuration without, so atoms want to be in them. It's quantum. You typically don't get to know the process in detail until your third year.
 
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If you consider the noble elements, there is also the London forces (also called van der Waals' forces) to consider.
 
The bonding results from electrons being attracted to both nuclei at the same time.
Since each C atom has an incomplete shell the electrons of the other atom can approach its nucleus.
Promotion of 2s -> 2p enhances the effect.
For full shell atoms Pauli repulsion prevents this. In such a case there is only the much weaker Van der Waals interaction.
 
Simon Bridge said:
Covalent bonds form when atoms share electrons ... physically the configuration with the shared electrons has a higher binding energy than the configuration without, so atoms want to be in them. It's quantum. You typically don't get to know the process in detail until your third year.
That's what I like to hear. Thanks.
 
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No worries.
 
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