How do free electrons in metals interact with and reflect photons?

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Free electrons in metals interact with photons primarily through absorption and re-emission processes. Although these electrons are not bound to specific energy levels, they can still absorb energy from incoming photons, leading to temporary excitation. The energy absorbed does not necessarily correspond to a drop to a lower atomic energy level, as free electrons exist in a continuum of energy states. The discussion highlights the complexity of electron behavior in solids, where collective interactions can influence photon reflection. Understanding these interactions is crucial for applications in optics and materials science.
Pranav Jha
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How do free electrons of metals reflect photons?
I had read that they first absorb and then emit the photon but if they are free (not bound to an atom and thus not fixed to any old energy level) why should they lose their energy on the first place? Surely they don't have to drop to their original atomic energy level.
 
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When we talk about atoms together in a solid, the electrons do not have discrete energy levels. There is an FAQ question that talks about photons moving through a solid medium and it may help to read it.
 
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