How Do You Determine Which Reaction to Flip in a Voltaic Cell?

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To determine which reaction to flip in a voltaic cell, identify the half-cell with the more negative standard reduction potential, as this half-cell will undergo oxidation. In this case, the Mn/Mn2+ half-cell has a more negative potential (-1.18 V) compared to the Cd/Cd2+ half-cell (-0.40 V), indicating that Mn will be oxidized and Cd will be reduced. The Nernst equation can then be applied using the oxidation potential of Mn and the reduction potential of Cd to calculate the concentration of Cd2+. The cell potential is calculated by combining the oxidation and reduction potentials, necessitating a sign change for the oxidation potential. Understanding these principles allows for accurate calculations of concentrations in electrochemical cells.
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Homework Statement



A voltaic cell at 25oC consists of Mn/Mn2+ and Cd/Cd2+ half-cells with an initial cell potential of +0.768 V. The [Mn2+] concentration is 0.500 M. Use the Nernst equation to calculate the [Cd2+] concentration in the Cd/Cd2+ half-cell.
Cd+2(aq) + 2e- = Cd(s) . . . . . Eo = -0.40 V
Mn+2(aq) + 2e- = Mn(s) . . . . . Eo = -1.18 V


Homework Equations



Ecell = E(standard) cell - (RT/nF)ln Q

The Attempt at a Solution



I was just wondering how do we know which reaction above, we need to flip and how do we determine which metal is oxidized and reduced in cells like this? Is it that the half-cell woth the more negative potential is more redilly reduced, thus that's the one you flip, to create the cell?
I know how to use the nerst equation and find concentration, but am having trouble with Enot Cell because i don't know which eqn to flip.
 
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What and why do you want to flip?

All you need is

EMn/Mn2+ = ECd/Cd2+
 


How is EMn/Mn2+ = ECd/Cd2+ ?
EMn/Mn2+ = -1. 18 and ECd/Cd2+= -0.40

The potential given is the E(reduction), if we use the equation E(cell) = E(oxidation) + E(reduction). Then we need to change the sign of one of the potentials to get that reactions E(oxidation).
 
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