A prism with a refractive index n alters the angle between two parallel light rays as they emerge. The discussion centers on applying Snell's law to determine the angle after refraction. Daniel initially struggles with the calculations but refines his approach by considering the geometry of the situation. He concludes that the angle between the rays after emerging can be expressed as 2[arcsin(n*sin(theta)) - theta]. The conversation emphasizes the importance of understanding both refraction and geometric principles in solving the problem.