Cadaei said:
I think I'm missing something extremely simple here... why is dotting ⟨X_I| into |psi_i⟩ the same as evaluating psi_I at X_I?
And yes, you need to know the difference between state vector |\Psi \rangle and its coordinate representation, i.e. wave-function \Psi ( x). Almost all textbooks explain the Bra-Ket notations and their connection to “wave-functions”.
You seem to have no problem with \langle \Phi | \Psi \rangle = \int dx \ \Phi^{*} (x) \Psi (x) . \ \ \ \ (A) Okay, let us work on the left-hand side by inserting the completeness relation 1=\int dx |x\rangle \langle x|:
\langle \Phi | \Psi \rangle = \langle \Phi | ( \int dx |x \rangle \langle x | ) | \Psi \rangle = \int dx \ \langle \Phi | x \rangle \langle x | \Psi \rangle .
Now, if you compare the RHS of this equation with the RHS of Eq(A), what would you get?
Similar state of affair exists in elementary vector algebra. You know how to expand a vector |\vec{V}\rangle in terms of some orthogonal unit-vectors | e_{i}\rangle |\vec{V}\rangle = \sum_{i} V_{i} \ | e_{i} \rangle .\ \ \ \ (1) You also know the ortho-normality condition \langle e_{i} | e_{j} \rangle = \delta_{ij} . \ \ \ \ \ \ \ (2) You should also know how to calculate the components of the vector from V_{i} = \langle e_{i} | \vec{V}\rangle . \ \ \ \ \ \ \ (3) You can now substitute (3) in (1) to obtain another familiar equation in vector algebra | \vec{V} \rangle = \sum_{i} | e_{i}\rangle \langle e_{i} | \vec{V} \rangle . \ \ \ \ \ \ (4) This leads to the completeness relation for the unit vectors \sum_{i} | e_{i} \rangle \langle e_{i}\rangle = 1 . \ \ \ \ \ \ (5) And finally, you know the scalar product \langle \vec{V}| \vec{U} \rangle = \sum_{i} V^{t}_{i} U_{i} .\ \ \ \ \ (6) Now, imagine the vector space to be an infinite-dimensional complex vector space spanned by un-countable infinity of ortho-normal functions (vectors) |e(x)\rangle \equiv | x \rangle, i.e. just pass to the continuous limits i \to x , \ \ \ | e_{i}\rangle \to | x \rangle , \ \ \sum_{i} \to \int dx , and V_{i} \to V(x), \ \ \ V^{t}_{i} \to V^{*}(x) . So, we can translate Eq(1)-Eq(6) into the continuous language as follow \mbox{Eq(1)} \to \ \ \ | V \rangle = \int dx \ V(x) \ | x \rangle , \mbox{Eq(2)} \to \ \ \ \langle x | y \rangle = \delta (x - y) . \mbox{Eq(3)} \to \ \ \ V(x) = \langle x | V \rangle , which is what you were asking about \Psi (x) = \langle x | \Psi \rangle. \mbox{Eq(4)} \to \ \ \ | V \rangle = \int dx \ | x \rangle \langle x | V \rangle . \mbox{Eq(5)} \to \ \ \ \int dx \ | x \rangle \langle x | = 1 . And finally the equation you know \mbox{Eq(6)} \to \ \ \langle V | U \rangle = \int dx \ V^{*}(x) U(x) .