How can the acidity constant of water in itself be defined?

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The discussion revolves around defining the acidity constant (Ka) of water itself. The proposed equilibrium equation for water dissociation is H2O + H2O ↔ H3O+ + OH-, leading to the calculation Ka(H2O) = Kw/[H2O]. However, the challenge arises in determining whether water can be considered in a "dilute solution" for this context, as the concentration of dissociation products is very small compared to that of water. Participants debate the validity of using activities instead of concentrations, noting that the activity of water is typically considered to be equal to 1. Ultimately, the conversation highlights the complexities in defining the acidity constant of water and the implications of concentration assumptions.
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Sorry if this question has already been asked but I didn't find it in this forum.

Which is the acidity constant of water in itself?

Ka of a weak acid HA in water dilute solution is defined considering the aequilibrium:

HA + H2O ↔ H3O+ + A- (1)
then:
Ka(HA) = [H3O+]⋅[A-] / [HA]

this, for what I know, because in dilute solution [H2O] is constant and can then be "incorporated" in the aequilibrium constant Keq:

Keq. = [H3O+]⋅[A-] / [HA]⋅[H2O]

Ka = Keq⋅[H2O] = constant1⋅constant2.

So, my "natural" guess to how Ka(H2O) can be defined, would be to replace HA with H2O in the aequilibrium (1) and then as follow.
Let's consider the aequilibrium:

H2O + H2O ↔ H3O+ + OH-

then:

Ka(H2O) = [H3O+]⋅[OH-] / [H2O] = Kw/[H2O] = 10-14/(1000/18) = 10-15.7.

But there is a problem: can I here really consider the acid H2O as in "dilute solution"? It seems meaningless...

How would you define the acidity constant of water in itself, in case is definible?

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"Dilute solution" in this context typically means "water concentration can be assumed to be constant".

Does it hold for water dissociation? (Hint: compare concentration of dissociation products with concentration of water itself).
 
Borek said:
"Dilute solution" in this context typically means "water concentration can be assumed to be constant".

Does it hold for water dissociation? (Hint: compare concentration of dissociation products with concentration of water itself).
From your answer I deduce that my definition of Ka(H2O) is correct. Is it?
Now let's see it from the point of view of activities.
Concerning [H3O+]and [OH_] there is no problem because they are so small to be certainly equal to their activities. But the activity of water is (or it should be) equal to 1. Is it correct?
But then Ka(H2O) should be equal to Kw = 10-14 and not 10-15.7.

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