You have already calculated Cx correctly, by noting that the sum of the x forces must equal zero, for equilibrium . Since Ax = 0 due to the roller support at A, Cx is 100N acting to the left on the bracket. That is to say,
Ax +Bx +Cx =0
0 + 100 + Cx =0
Cx =-100N
Now you look at forces in the y direction. They also must sum to zero.
Ay +By + Cy =0
You know the value of By, but you don't know Ay or Cy yet, so you need one more equation of equilibrium, which is
"Sum of Moments of all Forces about any Point =0."
If you choose point C as your point about which to sum moments, then calculate the moment about C from By (which you did), the moment from Bx (which you did not do), and the moment from Ay (which you did, in terms of Ay, an unknown), and add them all up, set them equal to zero, and solve for Ay. When you sum moments, watch your plus and minus signs; if you choose a clockwise moment as minus, then a counterclockwise moment is plus. Note that the forces at C do not contribute any moment when you sum moments about C. Once you solve for Ay, then you can get Cy from your Ay +By + Cy =0 equation.