How to find the concentration of CO2 in 1M NAOH solution?

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    Co2 Concentration
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Discussion Overview

The discussion revolves around the analysis of a liquid sample after conducting an absorption experiment of CO2 from air using a 1M NaOH solution. Participants explore methods to determine the concentration of CO2 based on changes in NaOH concentration before and after the experiment.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant suggests that measuring the difference in NaOH concentration before and after the absorption experiment provides the concentration of CO2, questioning if this is the correct approach.
  • Another participant acknowledges the approach as not wrong but describes it as tricky, referencing Warder titration as a comparison.
  • A participant explains their method of titrating both the inlet NaOH solution and the outlet solution against HCl, raising concerns about the reaction of Na2CO3 with HCl, which could regenerate NaOH and lead to similar concentrations in both solutions.
  • Another participant points out the importance of selecting the correct indicator for the titration process.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the best method for analyzing the liquid sample, and multiple competing views regarding the titration process and its implications remain evident.

Contextual Notes

There are unresolved aspects regarding the reactions occurring during titration, particularly the regeneration of NaOH from Na2CO3 and its impact on concentration measurements.

Pollyannaism
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I done the absorption experiment i.e absorption of CO2 from air using 1M NaOH .Can anyone please tell how to analyse the Liquid sample after absorption.

I found the concentration of NaOH after and before the experiment,difference in Concentration gives the concentration of CO2.is it the reight approach.
Any suggestion is appreciated..
 
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Pollyannaism said:
I found the concentration of NaOH after

How?

This is not a wrong approach, it is just a tricky problem. Compare Warder titration.
 
Thank you for replying..

I directly titrate the NaOH solution at inlet and also liquid solution from the column( outlet solution )against the HCl to find the concentration.My doubt is that when I tirate NaOH solution of the outlet ( contains Na2CO3 + unreacted NaOH) against HCl ,Na2cO3 reacts with Hcl to form NaOH again and CO2 will bubble out.So after doing the titration I am getting almost the same concentration(no significant difference)in both the solution.
 
Have you read the linked page? It is likely a matter of choosing correct indicator.
 

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