Hydrogen Emission Spectrum, Electrons, and Quantized Energy

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Discussion Overview

The discussion revolves around the hydrogen emission spectrum and its implications for the quantization of electron energy levels. Participants explore how the discrete wavelengths emitted by hydrogen relate to the behavior of electrons in terms of energy absorption and emission, focusing on the theoretical underpinnings of quantized energy states.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant notes that the hydrogen emission spectrum shows only certain wavelengths of light, suggesting that electrons emit light when relaxing and absorb light when excited, prompting a question about how this demonstrates energy quantization.
  • Another participant argues that if an electron can only absorb and release energy in discrete amounts, it implies that the electron can only have specific energy values, which are determined by the energies of the photons involved in the transitions.
  • A question is posed regarding the expected type of spectrum if electron energy were not quantized, asking whether it would result in single lines or a continuous spectrum.
  • A response asserts that a continuous spectrum would indicate non-quantized energy, reinforcing the idea that quantization is evidenced by the discrete energy shifts of electrons between ground and excited states.

Areas of Agreement / Disagreement

Participants express differing views on the implications of the hydrogen emission spectrum, with some supporting the idea of quantized energy levels while others question the interpretation of the spectrum's characteristics. The discussion remains unresolved regarding the broader implications of these observations.

Contextual Notes

Participants do not fully explore the assumptions underlying their claims, such as the definitions of energy states or the specific conditions of the hydrogen atom. The discussion also lacks a detailed examination of the mathematical framework that supports these concepts.

Who May Find This Useful

This discussion may be of interest to those studying quantum mechanics, atomic physics, or anyone looking to understand the relationship between atomic spectra and energy quantization.

Chrizappin
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I understand that the result of the hydrogen emission spectrum experiment was that only certain wavelengths of light were emitted and that led to the conclusion that electrons emit light when they relax and that they absorb light when they get excited. How does that prove that the energy for electrons are quantized?
 
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if an electron in a hydrogen atom can only absorb and release energy in discrete amounts, then whenever you measure the energy of an electron, it can only have one of a specific set of values (not counting an arbitrary zero point).

In short, if the electron has some energy E0, and it's changes in energy only come from photons with specific allowed frequencies, then the possible values of the energy of that electron will be E0 plus or minus the energies of the photons absorbed and emitted, respectively. We can set E0 to be any number we like, but that won't change the pattern of possible energy values that electron can have, only what counts as "zero".
 
What kind of a spectra would you expect to get from an electron if its energy were not quantized? Single lines, or a continuous spectrum?
 
We would have gotten
A continuous spectrum
If that's the case
The energy of an electron is quantised
Because it can shift from it ground state to its excited one
Only by absorbing discrete or fixed amounts of energy
That's what quantised means
 

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