Hydrophilic polymer that sublimes in vacuum

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A user is seeking a hydrophilic polymer that can sublimate in a vacuum of approximately 10-7 torr for a liquid mirror project, specifically to create a thin film barrier between a silver coating and an ionic liquid. Key requirements include hydrophilicity and semi-volatility, with a focus on minimizing surface irregularities. The discussion shifted towards small-molecule organic materials, which may be easier to sublime compared to polymers. Suggestions included using a parylene conformal coat followed by gold deposition, although alternatives like aluminum or chromium were also considered for their non-reactivity. Concerns were raised about the reactivity of silver with the ionic liquid, emphasizing the need for a stable barrier.
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I am trying to find a hydrophilic polymer that sublimes in vacuum (~ 10-7 torr).
Can anyone help me or tell me where i could find one?
 
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What properties do you require of the polymer other than hydrophilic and semi-semi-volatile?
 


Nothing else really, we don't need conductivity.
To tell a little more, I need a polymer to make a thin film (~20 nm) as a barrier between a silver coating and an ionic liquid. (this is for a liquid mirror project)
Polymer film is made by vacuum deposition, high temperature are obtained by ohmic heating.

-Silver coating has shown to make better bond with hydrophilic material (hence why hydrophilic polymer).
-Polymer sublimation helps to make a better surface on the liquid, less irregularities.

Those are the 2 most important properties.
 


edit. Let me think about this some...
 


I mixed things up, i am more looking for a small-molecule organic materials with said properties, this should be way easier to sublime.
 


You might try a parylene conformal coat followed by gold deposition and finally silver.
 


Thanks, but why gold? We were actually going to try an aluminium or chromium deposition instead.
 


I was going for non-reactive. You had some concerns regarding the reactivity of silver with the (unspecified) ionic liquid. It's a belt and suspenders thing...
 
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