Jan Wo
- 4
- 0
Hi
I'd like to ask you about interpretation of electron density definition. According to the "Handbook of Molecular Physics and Quantum Chemistry" it goes like:
##\rho (\textbf{r})=N \sum_{\sigma_1}^{\sigma_N} \idotsint_{\mathbb{R^3}} |\psi_V (\textbf{r}_1, \sigma_1;\dots ;\textbf{r}_N,\sigma_N)|^2 d^3\textbf{r}_2 \dots d^3\textbf{r}_N##
I know that my question may be a little imprecise so please - be patient. I'd like to know how to iterpret this definition. Why in the integral is only ##d^3\textbf{r}_2 \dots d^3\textbf{r}_N## but no ##d^3\textbf{r}_1d^3\textbf{r}_2 \dots d^3\textbf{r}_N##. How to explain this equation using physical viewpoint and how to explain it methematically ?
Feel free to add any helpful information to understand this definition.
Thanks in advance.
I'd like to ask you about interpretation of electron density definition. According to the "Handbook of Molecular Physics and Quantum Chemistry" it goes like:
##\rho (\textbf{r})=N \sum_{\sigma_1}^{\sigma_N} \idotsint_{\mathbb{R^3}} |\psi_V (\textbf{r}_1, \sigma_1;\dots ;\textbf{r}_N,\sigma_N)|^2 d^3\textbf{r}_2 \dots d^3\textbf{r}_N##
I know that my question may be a little imprecise so please - be patient. I'd like to know how to iterpret this definition. Why in the integral is only ##d^3\textbf{r}_2 \dots d^3\textbf{r}_N## but no ##d^3\textbf{r}_1d^3\textbf{r}_2 \dots d^3\textbf{r}_N##. How to explain this equation using physical viewpoint and how to explain it methematically ?
Feel free to add any helpful information to understand this definition.
Thanks in advance.