Iodine Clock Collision Theory Basic Question

Click For Summary
SUMMARY

The discussion centers on the Iodine Clock Reaction, specifically the Persulfate variation, and its relation to collision theory. The reaction involves the interaction of iodide ions (I−) and persulfate ions (S2O82−), leading to the formation of iodine (I2) and sulfate ions (SO42−). Participants highlight the complexity of determining specific collision orientations and mechanisms, noting that such details are often overlooked in inorganic chemistry compared to organic chemistry. The conversation suggests a need for further exploration of electrophilic addition in this context.

PREREQUISITES
  • Understanding of the Iodine Clock Reaction
  • Familiarity with collision theory in chemistry
  • Knowledge of reaction mechanisms in inorganic chemistry
  • Basic concepts of electrophilic addition
NEXT STEPS
  • Research the detailed mechanisms of the Iodine Clock Reaction
  • Study collision theory and its applications in chemical reactions
  • Explore electrophilic addition reactions in inorganic chemistry
  • Investigate the role of ion interactions in reaction kinetics
USEFUL FOR

Chemistry students, educators, and researchers interested in reaction mechanisms, particularly those focusing on the Iodine Clock Reaction and collision theory in both inorganic and organic contexts.

getfirefox
Messages
9
Reaction score
0
Hey guys. Any chemistry experts around?

I just did Persulfate variation of the iodine clock experiment.

http://en.wikipedia.org/wiki/Iodine_clock_reaction

According to collision theory explained on this page, molecules need to hit each other in certain positions to react.

Which molecule needs to hit which and in what direction in the iodine clock reaction?

2I(aq) + S2O82−(aq) → I2 (aq) + 2SO42−(aq)

and

I2 (aq) + 2S2O32−(aq) → 2I(aq) + S4O62−(aq)

Thanks guys!
 
Chemistry news on Phys.org
I doubt you will find an answer - reaction mechanisms are researched mostly in organic chemistry, in inorganic they are not that important, so they are usually ignored.

Note that asking "which molecule needs to hit which" doesn't make much sense - they collide, so in a way each hits each.

--
methods
 
Borek said:
I doubt you will find an answer - reaction mechanisms are researched mostly in organic chemistry, in inorganic they are not that important, so they are usually ignored.

Note that asking "which molecule needs to hit which" doesn't make much sense - they collide, so in a way each hits each.

Yeah sorry if that was worded poorly.

Doesn't it have something to do with electrophilic addition or something though? The iodine being attracted to a positive bond somewhere (maybe the sulphur?). I really don't know but I sort of need to have an idea.

:(
 

Similar threads

  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 1 ·
Replies
1
Views
5K
  • · Replies 2 ·
Replies
2
Views
8K
Replies
3
Views
13K
  • · Replies 1 ·
Replies
1
Views
8K
Replies
1
Views
6K
  • · Replies 6 ·
Replies
6
Views
36K
  • · Replies 266 ·
9
Replies
266
Views
31K
  • · Replies 11 ·
Replies
11
Views
6K
  • · Replies 8 ·
Replies
8
Views
5K