Iodine Clock Collision Theory Basic Question

AI Thread Summary
The discussion centers on the iodine clock reaction, specifically the persulfate variation. Participants are exploring the collision theory in relation to the reaction mechanisms involved. The key reaction equations are presented, highlighting the interaction between iodide ions and persulfate ions, leading to the formation of iodine and sulfate ions. There is a recognition that understanding which molecules need to collide and in what orientation is complex, as the nature of molecular collisions means that all reactants interact. The conversation also touches on the relevance of electrophilic addition, suggesting that the iodine may interact with positive sites, possibly on sulfur. Overall, there is a consensus that reaction mechanisms are less emphasized in inorganic chemistry compared to organic chemistry, leading to some uncertainty about the specifics of molecular interactions in this context.
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Hey guys. Any chemistry experts around?

I just did Persulfate variation of the iodine clock experiment.

http://en.wikipedia.org/wiki/Iodine_clock_reaction

According to collision theory explained on this page, molecules need to hit each other in certain positions to react.

Which molecule needs to hit which and in what direction in the iodine clock reaction?

2I(aq) + S2O82−(aq) → I2 (aq) + 2SO42−(aq)

and

I2 (aq) + 2S2O32−(aq) → 2I(aq) + S4O62−(aq)

Thanks guys!
 
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I doubt you will find an answer - reaction mechanisms are researched mostly in organic chemistry, in inorganic they are not that important, so they are usually ignored.

Note that asking "which molecule needs to hit which" doesn't make much sense - they collide, so in a way each hits each.

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Borek said:
I doubt you will find an answer - reaction mechanisms are researched mostly in organic chemistry, in inorganic they are not that important, so they are usually ignored.

Note that asking "which molecule needs to hit which" doesn't make much sense - they collide, so in a way each hits each.

Yeah sorry if that was worded poorly.

Doesn't it have something to do with electrophilic addition or something though? The iodine being attracted to a positive bond somewhere (maybe the sulphur?). I really don't know but I sort of need to have an idea.

:(
 
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