Calculating ECell of Anode-Half Cell? Chemistry Review

In summary, the redox reaction of peroxydisulfate with iodide is commonly used in the iodine clock reaction for teaching kinetics. With a given E°cell of 1.587 V and E° of the cathode half-cell at 0.536 V, the E° of the anode half-cell can be calculated using the formula E°cell = ECathode - EAnode. However, it is not specified which entity is being reduced and which is being oxidized, so it is not possible to determine the sign of the contribution to voltage.
  • #1
Blockmeister
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Homework Statement


The redox reaction of peroxydisulfate with iodide has been used for many years as part of the iodine clock reaction which introduces students to kinetics. If E°cell = 1.587 V and E° of the cathode half-cell is 0.536 V, what is E° of the anode half-cell?

S2O82–(aq) + 2H+ + 2I–(aq) → 2HSO4–(aq) + I2(aq)



Homework Equations


I think ECEll= ECathode-EAnode

but not sure



The Attempt at a Solution



have no idea
 
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  • #2
Voltage is calculated in reduction potentials. Which entity is being reduced and which is being oxidized? If the reduction potential of one entity is a positive number, what is the sign of the contribution to voltage if the entity is being oxidized?
 

1. What is the formula for calculating ECell of an Anode-Half Cell?

The formula for calculating ECell of an Anode-Half Cell is ECell = EAnode - ECathode, where EAnode is the standard electrode potential of the anode and ECathode is the standard electrode potential of the cathode.

2. How do I determine the standard electrode potential of an anode?

The standard electrode potential of an anode can be found in a standard electrode potential table. This table lists the standard electrode potentials of different half cells at standard conditions.

3. Can ECell be negative?

Yes, ECell can be negative. A negative ECell value indicates that the reaction is not spontaneous. This means that the anode is not strong enough to oxidize the species in the cathode half cell.

4. What is the significance of ECell in electrochemical reactions?

ECell is a measure of the potential difference between the anode and cathode half cells. It determines whether a redox reaction is spontaneous or non-spontaneous. A positive ECell value indicates a spontaneous reaction, while a negative ECell value indicates a non-spontaneous reaction.

5. How does temperature affect the calculation of ECell?

Temperature can affect the standard electrode potentials used in the ECell calculation. As temperature increases, the standard electrode potential of a half cell may also change. Therefore, it is important to use the standard electrode potentials at the same temperature when calculating ECell.

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