Is the Classical Electric Potential a Valid Approximation in Quantum Mechanics?

cragar
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When we setup the Schrodinger equation for the hydrogen atom we use the classical electric potential. It seems that we would need a new potential instead of mixing QM and classical.
Is this just a very good approximation or is there something subtle.
 
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cragar said:
When we setup the Schrodinger equation for the hydrogen atom we use the classical electric potential. It seems that we would need a new potential instead of mixing QM and classical.
Is this just a very good approximation or is there something subtle.

It's a very good approximation. For one, relativistic corrections exist (but that's not what you're asking) that come about with the Dirac Equation. As for your question, in what is termed "Second Quantization", the electromagnetic potential can also be quantized. This is the field of Quantum Electrodynamics (QED). It provides the most accurate framework for including the electromagnetic potentials.
 
thanks for your answer. if its not to much trouble how do they correct for relativity in the potential.
 
Insights auto threads is broken atm, so I'm manually creating these for new Insight articles. Towards the end of the first lecture for the Qiskit Global Summer School 2025, Foundations of Quantum Mechanics, Olivia Lanes (Global Lead, Content and Education IBM) stated... Source: https://www.physicsforums.com/insights/quantum-entanglement-is-a-kinematic-fact-not-a-dynamical-effect/ by @RUTA
If we release an electron around a positively charged sphere, the initial state of electron is a linear combination of Hydrogen-like states. According to quantum mechanics, evolution of time would not change this initial state because the potential is time independent. However, classically we expect the electron to collide with the sphere. So, it seems that the quantum and classics predict different behaviours!
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