Here some quotes about the hydrogen collecting up in the buildings:
Borek said:
I am not so sure about stratification. Bubbles of pure hydrogen will go up, no doubt about it. But if the gases are well mixed, from what I remember stratification due to masses of molecules is negligible, as mixing due to thermal motion is way too strong. For reasonably good results you need very high towers and very low temperatures (cryogenic distillation) - neither were present.
Jorge Stolfi said:
Hydrogen/oxygen mixtures can be ignited by contact with a suitable catalyst, such as certain bare metals. The catalyzer will initially combine H2+O2 flameless, but will get hot as a result. (The explosion that convinced Fleischmann and Pons that they had achieved cold fusion was later conjectured to be a chemical D2 + O2 explosion catalyzed by palladium.)
Jorge Stolfi said:
No matter what the difference in density, gases that are mixed will stay mixed, and gases that are initially stratified will gradually diffuse into each other, even if they are kept perfectly still (without macroscopic motion). Indeed there must have been significant convection currents in the service floor of #4, because of the powerful heat+steam source in one corner.
That said, IMHO radiolysis seems a better explanation than H2 leakage from #3. I cannot see how a warm steam+H2 mixture, much lighter than air, would have chosen to travel backwards into the venting pipe of #4, and force its way through a tortuous path with several valves and tubing into a closed building with the AC turned off --- instead of flowing up the venting tower. I suppose that if some of the H2+steam from #3 managed to get into the chimney, it would have created negative pressure at its base, thus sucking back any gas that happened to flow towards #4
Just my unqualified 2 cents:
First of all, thanks to Nuceng and all the others for their valuable insights!
Please do also consider the fact that much, if not most of the steam will condensate at the walls etc due to the very low dew point.
The increased pressure even speeds up condensation.
This means that the mixture steam-hydrogen inevitably gets richer in hydrogen with time, because hydrogen cannot condensate under earthly temperatures/pressures.
Until explodable conditions have been achieved, Then just a little spark or hot surface could initiate the "kaboom procedure"...
The observation that only RB#2, the only that allowed hydrogen to escape, remained in shape, appears to confirm my hypothesis as far I see.
Compare this to a fridge where you put a pot of boiling water in. The steam will condense at the walls, some leaking out at the door, but not popping it open.
(Finally, due to lack of (pressed out) air the fridge will develop underpressure, making it difficult to open the door. Unlike a reactor...)
Consider this photo
just before explosion.
Do you also see steam leaving through building weak points at wall/ceiling corner of reactor building #1 (left)?
Doesn't this indicate high pressure in the reactor building?
(Or maybe I misinterpret this image ? It could be Daini or some other plant?!? But what is that optical distortion looking like steam? German "Spiegel" posted this photo short before Daiichi explosion #1, with picture description suggesting it was Daiichi 1+2...)
So, could the inevitable outcome have been that eventually an explosive hydrogen-oxygen ratio developed, ready to be ignited by a slight spark or some hot surface?