K, L, M electron transitions, x-ray emission lines, conflicting information

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SUMMARY

The discussion centers on electron transitions in x-ray fluorescence techniques, specifically EDX and XES. Key transitions include Kα (L to K shell), Kβ (M to K shell), and Kγ (N to K shell). Confusion arises from historical labeling, particularly regarding transitions like Lβ₂ (N to L) and Kβ₂ (N to K), as well as the significance of the numeral suffixes. These suffixes typically denote the ordering of distinct lines based on wavelength, often linked to different delta-J values.

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  • Understanding of electron transitions in atomic physics
  • Familiarity with x-ray fluorescence techniques such as EDX and XES
  • Knowledge of spectral line notation and its historical context
  • Basic principles of quantum mechanics related to electron energy levels
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  • Research the specifics of electron transitions in x-ray fluorescence
  • Study the historical context of spectral line notation
  • Learn about the significance of delta-J values in spectral lines
  • Explore the implications of electron transitions on x-ray emission lines
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Researchers in atomic physics, x-ray fluorescence analysts, and anyone seeking clarity on electron transition nomenclature and its implications in spectroscopy.

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So the basic understanding I have of electron transitions for EDX, XES and other x-ray fluorescence techniques is that a transition from:
L to K shell is named [itex]K\alpha[/itex]
M to K shell is [itex]K\beta[/itex]
N to K shell is [itex]K\gamma[/itex]
M to L shell is [itex]K\alpha[/itex]
etc.

Grand, easy... google leads me to multiple diagrams explaining it like this. But now I have a feeling that's a bit woolly and the real story is more convoluted. The http://xdb.lbl.gov/Section1/Sec_1-2.html" which shows [itex]L\beta _{2}[/itex] being an N to L transition and [itex]K\beta _{2}[/itex] being an N to K transition...

Can anyone explain to me why this is? Is there a physical logic to it or is it just from historical labeling of lines observed?

Also the last number, say [itex]L\beta _{2}[/itex], what does the 2 refer to? Is it the intensity of the line? The energy position?

Cheers
 
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http://en.wikipedia.org/wiki/K-alpha

It's confusing historical notation but people continue to use it anyway. I think in practice the 1, 2, etc. refers to the wavelength ordering of distinct lines, which I believe corresponds to different delta-J values but I won't swear that this is always the case.
 

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