Kittel, Chapter 7, Central Equation

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In summary, Kittel discusses the central equation for the Fourier components of waves in a periodic lattice, which is used to determine the wavefunctions. He explains that solving this equation is a difficult task and then explains how the coefficients for the wavefunction can be obtained by plugging it into the Schrodinger equation and using Fourier series. This method is a general way of solving differential equations, not specific to solid state or Bloch functions.
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DrBrainDead
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Homework Statement


Kittel states at page 172, that the central equation for the Fourier components of waves in a periodic lattice is given by:
([tex]\lambda[/tex]k-E)*C(k)+[tex]\sum[/tex]UG*C(k-G)=0

From this he goes on to say "Once we determine the C's from (27), the wavefunctions (25) is given as:

[tex]\psi[/tex]k(x)=[tex]\sum[/tex]C(k-G)*exp(i(k-G)x)

I'm completely in the blank about how he got the C's isolated and got the above equation for the wavefunction..any help?

Homework Equations



Equation 27:
([tex]\lambda[/tex]k-E)*C(k)+[tex]\sum[/tex]UG*C(k-G)=0

Equation 25:
[tex]\psi[/tex](x)=[tex]\sum[/tex]C(k)*exp(i(k)x)
 
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  • #2
He did not actually get the coefficients.
He even tells you that solving the equation is a very difficult task in general.
He tells what can be done after the equation is solved.

About how he gets the wave-function: he assumes that it can be written in the form (25), as a combination of plane waves, with various coefficient. (This form is like a Fourier expansion)
To find the coefficients, you plug in the function in Schrodinger eq (the one with Bloch functions) and you get some equations for the coefficients.

This is actually a quite general method of solving differential equations, by using Fourier series. Is not something specific for solid state or Bloch functions.
 

Related to Kittel, Chapter 7, Central Equation

1. What is the central equation in Kittel, Chapter 7?

The central equation in Kittel, Chapter 7 is the Schrödinger equation, which describes the behavior of quantum particles in a given potential.

2. Why is the Schrödinger equation important?

The Schrödinger equation is important because it allows us to understand and predict the behavior of quantum particles, which are the building blocks of matter.

3. What is the significance of the wavefunction in the central equation?

The wavefunction in the central equation represents the probability amplitude of finding a particle in a certain state or location, and it is the main quantity used to solve the Schrödinger equation.

4. How does the central equation relate to the uncertainty principle?

The central equation, which describes the behavior of quantum particles, is intimately connected to the uncertainty principle, which states that it is impossible to know both the position and momentum of a particle with absolute certainty.

5. Can the central equation be applied to macroscopic systems?

No, the central equation is only applicable to microscopic systems, such as atoms and particles, and cannot be used to describe macroscopic objects due to the principles of quantum mechanics.

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