Assuming we are dealing with a chemical basis for life, then there are couple of fundamental limits (absent technological creation of life): (1) Life seems to require complex chemicals, like RNA, in order to reproduce and diversify. That means you can't overheat them: Every bond in your hypothetical complex molecule has to be strong enough to withstand the heat of the environment long enough to reproduce. I suspect you will find that you need many atoms whose bonds are weaker than silicates to build up a sufficiently complex molecule, so you can't take silicates to be representative of high-temperature biochemistry. (This is not my area of expertise, though, so perhaps someone with a high-temp chem background can weight in.)
(2) There has to be enough time to evolve those complex chemicals. Substantial levels of carbon and other non-hydrogen atoms have only existed for a few billion years longer than on Earth. (And the entire universe less than 10 GY longer.) Not a short time, to be sure, but if you wait for (e.g.) ethane-based chemistry on a cold world like Titan, you may have to wait far longer than that to produce complex chemistry, because the reactions slow down so dramatically as the temperature falls.