Michelson Interferometer IR Lab Question

Click For Summary

Discussion Overview

The discussion revolves around the operation and application of the Michelson Interferometer in the context of Fourier Transform Infrared Spectroscopy (FT-IR). Participants explore the theoretical principles and practical setup of the interferometer, particularly how it interacts with samples during analysis.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant outlines the components of the Michelson Interferometer and its role in obtaining molecular vibrational data from organic compounds using infrared radiation.
  • Another participant suggests that the sample does not become part of the interferometer but rather that the interferometer serves as a sophisticated radiation source before the radiation interacts with the sample.
  • A third participant seeks clarification on the process, asking if the intensity values of the beam without the sample are compared to those with the sample at various intervals of the movable mirror.
  • A fourth participant reiterates the idea that the radiation passes through the sample after going through the interferometer, implying a shared path for the radiation.

Areas of Agreement / Disagreement

Participants express differing views on the role of the sample in the interferometer setup, with some suggesting it acts as a separate entity rather than a component of the interferometer itself. The discussion remains unresolved regarding the specifics of how the sample interacts with the radiation in the context of the interferometer.

Contextual Notes

There are limitations in the discussion regarding the precise mechanics of the interferometer's operation and the assumptions about the path of radiation through the system. Participants have not fully clarified the mathematical or physical principles governing the comparison of intensity values.

BrainHurts
Messages
100
Reaction score
0
I've been reading up on Fourier Transform Infrared Spectroscopy and the Michelson Interferometer. My main sources are "Principles of Instrumental Analysis" by Skoog etc and Fourier - Transform Infrared Spectrometry by Griffiths and Haseth.

I believe I understand the theoretical principles behind the Michelson Interferometer. We may obtain molecular vibrational data by exposing molecules to infrared radiation. Experimentally, FT-IRs use some sort of interferometer to obtain this vibrational data.

I get that the basic Michelson Interferometer is comprised of: a fixed mirror, a beam splitter, a movable mirror, a source and a detector. I understand that the variation in the intensity of the beams passing to the detector and returning to the source as a function of the path difference yields the desired spectral information.

My question: When you analyze some organic compound, what part of the Michelson Interferometer does it become? When you hit your sample with the radiation, does it take place of the Fixed Mirror? I guess that's what I don't understand. I haven't studied chemistry of physics in awhile so any clarification would be highly appreciated.
 
Chemistry news on Phys.org
I don't remember details about how it works (so I can be off), but it is not that the substance becomes "a part" of the interferometer. Radiation goes through the interferometer first, and then through the sample, in a way interferometer is used just as a sophisticated radiation source.
 
I wish I knew how to draw a diagram. Let me see if I understand what you're saying.

So the radiation goes through the interferometer first (as a reference), then the radiation goes through the sample. Do you then compare intensity values of the beam no sample to the intensity values of the beam with sample at various time intervals of the movable mirror?
 
And the sample is hit with radiation and the radiation goes through the sample to which this radiation goes through the same Michelson Interferometer path?
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
1K
  • · Replies 1 ·
Replies
1
Views
1K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 24 ·
Replies
24
Views
3K
  • · Replies 5 ·
Replies
5
Views
1K
Replies
1
Views
2K
Replies
7
Views
1K
  • · Replies 33 ·
2
Replies
33
Views
4K
  • · Replies 6 ·
Replies
6
Views
4K
  • · Replies 29 ·
Replies
29
Views
7K