There are two major mechanisms of food heating in a microwave heating:
1.dipole rotation: because water is a molecular dipole, it is influenced by the alternating electric field component of the electromagnetic wave. The water molecule attempts to follow the alternating electric field, however, it lags behind the field, thereby gaining energy from the field that is stored as kinetic energy. As the field collapses to zero it gives up his energy in the form of random kinetic energy, which is a definition of heat. There may also be collisions between the water molecules that also will be manifested as heat.
2.ionic conduction: this heating mechanism is based upon the presence of ionic species such as sodium and chloride ions, present when salt disassociates in solution. In this case, each of the ions as an different charge, and as the electric field alternates, these ions are accelerated in opposite directions, colliding with unionized water molecules which, in turn, collide with other molecules. When the field collapses to zero and then builds up in the opposite polarity the ionic species move in the opposite direction again causing collisions, and again these are manifested as random kinetic energy, or the equivalent of heat.
What is strange about both of these mechanisms is that the ultimate healing effects are quite different. As water gets hotter it heats much more slowly: in other words, cold water heats faster than hot water. On the other hand, if their is salt present, the solution heats faster as it gets hotter causing something known as “thermal runaway”, which is extremely difficult to control.