The discussion centers on the complexity of molecular ionization compared to the Rydberg formula, which is applicable only to hydrogen-like atoms with a single electron. While it may be possible to derive specific formulas for certain cases of molecular ionization, these would lack the fundamental significance of the Rydberg equation, often being considered mere numerology. The conversation also references Rydberg ionization spectroscopy as a related topic, highlighting the limitations of applying the Rydberg formula to more complex molecular systems.