My textbook says electrolytes conduct electricity by the Movement of

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Discussion Overview

The discussion revolves around the conductivity of electrolytes, specifically focusing on the movement of ions versus electrons, the solvation of ions in water, and the nature of electrical current in solutions. It also touches on related topics such as the behavior of water molecules in the presence of ions and the properties of other materials like graphite and diamond.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant notes that electrolytes conduct electricity through the movement of positive and negative ions, contrasting this with the idea of free electrons being responsible for conductivity.
  • Another participant emphasizes that ions are solvated by water molecules, suggesting that solvation is more about the ordering of water dipoles rather than a chemical reaction.
  • A question arises regarding whether valence electrons leave the shells of ions during this process, with a clarification that they do not.
  • Concerns are raised about the nature of electrical energy and whether current is merely a conventional idea, with a response indicating that current is defined as the flow of electric charge, which can include ions.
  • Participants discuss the disruption of water structure by ions, noting that while this occurs, it does not necessarily imply a chemical reaction takes place.
  • One participant asks about the electrical conductivity of molten graphite and diamond, introducing a new topic related to electrical properties of materials.
  • Another participant inquires about the behavior of atoms, molecules, and ions when compounds boil, indicating a curiosity about phase changes.

Areas of Agreement / Disagreement

Participants generally agree on the role of ions in conducting electricity and the nature of solvation, but there are ongoing questions and clarifications regarding the specifics of these processes. The discussion remains unresolved on certain points, particularly concerning the implications of water structure disruption and the nature of electrical energy.

Contextual Notes

Some statements about the interactions between ions and water may depend on specific conditions and concentrations, and the discussion does not resolve the complexities involved in these interactions.

Who May Find This Useful

This discussion may be useful for students and enthusiasts interested in electrochemistry, the behavior of solutions, and the fundamental principles of electricity and conductivity in various materials.

Celluhh
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My textbook says electrolytes conduct electricity by the
Movement of positive and negative ions. I have always thought it was due to the movement Of free electrons but it isn't so . Why is this so ? I have visited a few websites but am unable to reach an answer . By the way, when we say ionic compounds dissolve , other than dissociating , they also form bonds with water molecules right? Is this the same as reacting with water? Do thy form new ions with water molecules ?? And most importantly , how exactly do mobile ions conduct electricity in electrolytes ?? Thanks in advance !
 
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Generally there are no free electrons in the solution, so this option (movement of free electrons) is out of the question.

Ions are getting solvated by water molecules - in a way you can think about solvation not as about chemical reaction, more like ordering of water dipoles just by electrostatic forces (that's not always true, but let's not confuse things further). Solvated ions float in the solution and can freely move.

An electrical current is a movement of a charge - doesn't matter if the charge is in the form of electrons or ions. If it is charge, and it moves, you have an electric current.
 


If I understand u correctly , ur saying the valence electrons don't actually leave the shells of the ions ?
And the solvated ions do not actually break hydrogen bonds between
Water molecules and form hydrogen bonds with water molecules themselves ? They just remain as they are in the solution ?

But in electricity electrons are the ones with electrical energy ? Isn't current just a conventional idea ?
 


Celluhh said:
If I understand u correctly , ur saying

Please, no textspeak at PF.

the valence electrons don't actually leave the shells of the ions ?

They don't.

And the solvated ions do not actually break hydrogen bonds between
Water molecules and form hydrogen bonds with water molecules themselves ? They just remain as they are in the solution ?

Presence of ions disrupts to some extent water structure, as molecules around ions are getting ordered. To what extent depends on the solution concentration.

But in electricity electrons are the ones with electrical energy ? Isn't current just a conventional idea ?

No idea what you mean by "electrical energy", everything I can think of is related to charge, not electrons. Electrons happen to be charge carriers, but not the only ones. Current is a flow of an electric charge through the medium, that's a definition, not a "conventional idea".
 


Ok so even if water molecules are disrupted , no chemical reaction actually takes place ??
 


Oh and sorry for using text speak !
 


Celluhh said:
Ok so even if water molecules are disrupted , no chemical reaction actually takes place ??

That's the first approximation.

Every ion is different and things can get complicated when you look at details, but even if there are some reactions between ions and water they don't change the way charge is transported in the solution.
 


Ok thank you !
 


Uh by the way, this is off topic, but is molten graphite and diamond and other giant covalent structures electrical conductors ??
 
  • #10


Oh and , compounds can boil right? What happens to the atoms and molecules and ions when they are boiled ?
 
  • #11


If you have unrelated questions, please start a new thread.
 

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