Hmm.. Here's what I've got:
<br />
\begin{align*}<br />
V &= \frac{1}{3}r\sqrt{1 - \pi^2r^4}\\<br />
V' &= \frac{1}{3}\sqrt{1 - \pi^2r^4} + \frac{1}{3}r\frac{1}{2}(1 - \pi^2r^4)^{-1/2}(-4\pi^2r^4)\\<br />
&= \frac{1}{3}\sqrt{1 - \pi^2r^4} - \frac{2\pi^2r^4}{3\sqrt{1 - \pi^2r^4}}\\<br />
&= \frac{1 - \pi^2r^4 - 2\pi^2r^4}{3\sqrt{1 - \pi^2r^4}}\\<br />
&= \frac{1 - 3\pi^2r^4}{3\sqrt{1 - \pi^2r^4}}\\<br />
\end{align*}<br />
This is the same thing the derivative calculator got, but it factored the denominator. It looks like you only made a minor mistake. Anyway, to find critical points, you want to know where the derivative is 0 or undefined. The derivative will be undefined when its denominator is 0, but in problems like these, the critical point you're looking for usually comes from setting the derivative equal to 0 and solving.